Past exam of the astrophysical fluid dynamics course of the University of Cambridge / 2017 / 4 / e

Retain the preceding isothermal assumption, so the gas temperature remains $T_0$. When two neutral hydrogen atoms become one molecular hydrogen molecule, the mean particle mass doubles. At fixed mass density and temperature the ideal gas law would halve the pressure, but the flowing gas is free to compress and change speed. It cannot in general keep density, pressure, and velocity all unchanged.

To describe a thin steady transition, label the atomic and molecular sides by $1$ and $2$ and neglect the integrated external force and radiative recoil across its small thickness. Local mass conservation and momentum conservation requireThe isothermal sound speed changes from $a_1^2=k_B{T}_0/m_H$ to $a_2^2=a_1^2/2$. Dividing the momentum flux by $j$ gives $u_2+a_2^2/u_2=J$, with $J=u_1+a_1^2/u_1$. The subsonic continuation is thereforeThus the gas becomes denser and slower. In the well-subsonic limit, where ram stresses are small compared with thermal pressure, the useful leading description of isothermal flow through molecular hydrogen formation isThe exact momentum condition gives a small pressure increase at low Mach number, rather than an imposed discontinuous factor-of-two pressure drop. The full expressions above apply when the subsonic speed is not asymptotically small.

Radiation of the molecular binding energy prevents that released energy from automatically heating the gas. It does not, by itself, determine the temperature: the constant-temperature result uses the inherited isothermal closure. If that assumption is relaxed, an energy equation including cooling and molecular degrees of freedom is needed; the wording about emitted binding energy alone does not uniquely determine all four changes.