A phonon is one quantum of a collective harmonic normal mode of a crystal. A mode labelled by wavevector and branch has energies , with bosonic occupation statistics. The crystal momentum is defined modulo a reciprocal lattice vector; it is not generally the mechanical momentum of one atom. The phonon dispersion relation assigns its frequency and polarization to the wavevector and branch.
Inelastic neutron scattering can measure this relation in a single crystal. Determine the incident neutron energy and wavevector, scatter at a chosen angle, and analyze the outgoing energy by time of flight or a spectrometer analyzer. Energy and crystal-momentum conservation giveThe signs distinguish phonon creation and annihilation with consistent momentum convention. Repeating measurements at different momentum transfers maps peaks in the dynamic scattering response into phonon branches. The measured intensity depends on occupation, scattering factors and the projection of the mode polarization along the momentum transfer; a weak or missing peak need not mean that the corresponding mode does not exist.
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