Past exam of the condensed matter physics major option course of the University of Oxford / 2018 / 4 / a

Seek the steady forced displacement as $x=x_0{e}^{-i\omega t}$. The oscillator equation givesFor $n$ ion pairs per volume, the ionic polarization is $P_{\mathrm{ion}}=nqx$. Add the electronic polarization ${ϵ}_0({ϵ}_{\infty }-1)E$, assumed frequency-independent over this infrared range. The complex relative permittivity is thereforeFor a longitudinal free oscillation without external free charge, $\mathbf{k}\cdot \mathbf{D}=0$ and the longitudinal electric field requires ${ϵ}_r({\omega }_{\mathrm{LO}})=0$ in the lossless limit. HenceEliminating the microscopic oscillator strength givesHere ${\omega }_{\mathrm{LO}}$ denotes the undamped longitudinal frequency; with finite damping the zero is at a complex frequency. The sign of the imaginary term follows the stated $e^{-i\omega t}$ convention and gives positive absorptive $\mathrm{Im}{ϵ}_r$ for $\omega >0$, $\gamma >0$. At zero frequency the same model yields the Lyddane-Sachs-Teller relation ${ϵ}_r(0)/{ϵ}_{\infty }={\omega }_{\mathrm{LO}}^2/{\omega }_{\mathrm{TO}}^2$. The high-frequency limit here is above the phonon resonance but below electronic resonances, not arbitrarily high photon energy.