Past exam of the mathematics course of the University of Cambridge / 2017 / ib / Paper 4 / 6B (Quantum Mechanics)

The wavefunction is a plane wave and a simultaneous formal eigenfunction of the momentum operator and the time-translation energy operator:Its momentum and energy are therefore definite, while its probability density is spatially uniform:For a particle of mass $m$, the probability current is $j=(\hslash /m)\mathrm{Im}(\overline{\varphi }{\partial }_x\varphi )=\hslash k{A}^2/m$, directed according to the sign of $k$.

On the whole real line, a nonzero constant-amplitude plane wave is not square-integrable and cannot be normalised to total probability one. It represents an idealised momentum eigenstate, interpreted through generalized eigenfunctions or as a limit of wave packets. Also, arbitrary $k,E$ do not automatically solve the Schrodinger equation for a specified potential energy: for a free particle, $E={\hslash }^2{k}^2/(2m)$, or this value plus the constant potential energy for a constant-potential region. If $A=0$, the zero function is not a physical quantum state.

For a finite potential energy discontinuity, the stationary state $\psi$ and its first derivative are continuous at $a$. Integrating the Time-independent Schrodinger equation across a shrinking interval about $a$ gives continuity of ${\psi }^{\prime }$; a jump in $\psi$ would produce a distributional derivative incompatible with a finite potential energy.

For $E>V_0$, put $k=\sqrt{2mE}/\hslash$, $q=\sqrt{2m(E-V_0)}/\hslash$ and use unit incident amplitude:There is no wave incident from the right. The matching equations $1+r=t$, $k(1-r)=qt$ give $r=(k-q)/(k+q)$ and $t=2k/(k+q)$. Comparing reflected and incident probability currents gives the reflection coefficientThe transmitted fraction is $T=(q/k)|t{|}^2=4kq/(k+q{)}^2$, so $R+T=1$.

For $0<E<V_0$, write $\kappa =\sqrt{2m(V_0-E)}/\hslash$ and retain only the decaying right-hand solution $t{e}^{-\kappa (x-a)}$. Matching gives $r=(k-i\kappa )/(k+i\kappa )$, which has modulus one. The evanescent wave carries no transmitted probability current. At $E=V_0$, the bounded right-hand solution is constant and matching again gives $r=1$. ThusClassically, a particle is wholly transmitted for $E>V_0$ and wholly reflected for $E<V_0$; there is no classical partial reflection above the step. At the threshold it has zero right-hand speed and no transmitted flux, a marginal case requiring a convention about motion exactly on the discontinuity. The quantum result approaches $R=0$ as $E/V_0\to \infty$.