For a time-independent Hamiltonian operator and a Schrödinger picture observable with no explicit time dependence, the Heisenberg picture operator is
Differentiation gives , so
If itself depends explicitly on time, one must add to ; the displayed commutator relation uses the usual convention of no explicit time dependence for the observable.
For a free real scalar field, the Lagrangian density contains its quadratic kinetic term and mass term:
The field's conjugate momentum is . The positive sign of the time-derivative term uses the metric convention fixed in Question 1.
Apply the Legendre transform in mechanics pointwise to the field Lagrangian density. Using , the Hamiltonian density is
The free Hamiltonian operator is its spatial integral:
A constant vacuum-energy subtraction, if made, does not affect the commutators or the ensuing field equation.
The canonical quantization of a real scalar field promotes the classical equal-time brackets to the canonical commutation relations, in units :
The Dirac delta distribution expresses locality of the conjugate variables. These are identities of operator-valued distributions, interpreted after spatial smearing where necessary.
Use the free Hamiltonian operator and the canonical commutation relations. The kinetic momentum term gives
The Heisenberg picture equation therefore yields .
For the momentum commutator, the mass term gives . The gradient term gives
where integration by parts differentiates the field instead of the Dirac delta distribution. Thus
Combining the two first-order operator equations gives the Klein-Gordon equation:
Suitable decay or spatial smearing removes the boundary term in the integration by parts.
For the two free real scalar fields, let . The infinitesimal internal rotation symmetry of two real scalar fields has and , with constant . Its kinetic terms are invariant because this is an orthogonal rotation of the two-component field.
Under the assumed invariance of the full Lagrangian density, Noether's theorem gives the current per unit transformation parameter:
The Noether current and Noether charge are therefore
Independent species commute at equal time, so these products require no extra ordering sign. With vanishing boundary flux, is conserved. Part (vii) checks precisely what the symmetry assumption requires of the masses.
Differentiate the Noether charge and use and the Klein-Gordon equation for each species. The momentum products cancel because the two species commute:
The first integral is the boundary flux of , so it vanishes under the same boundary condition used for charge conservation. Hence
Conservation must hold for arbitrary configurations, rather than only a state in which this particular integral happens to vanish. Thus the internal rotation symmetry of two real scalar fields requires
Equivalently, the local divergence is , exhibiting exactly how unequal masses break the symmetry.

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