Substitution into the diffusive flux givesThe continuity equation for this drift-diffusion equation with a potential therefore reduces, after cancelling the nonzero exponential, toThe reflecting boundary conditions become at both endpoints. Thus each solution of this eigenvalue problem supplies a separated solution of the original diffusion equation.
The product rule makes the drift term cancel:Consequently the transformed eigenvalue problem isBoth and the weight are positive, as required for this Sturm-Liouville problem.
For sufficiently smooth functions satisfying the same boundary conditions, integration by parts gives the boundary formThe stated endpoint relation annihilates this expression. This proves the required self-adjoint differential operator identity; for the usual regular Sturm-Liouville problem, separated real boundary conditions give a self-adjoint realization on its domain.
In this problem the transformed diffusive flux is . Thus the physical boundary conditions areequivalently when the endpoint values of are positive. In particular at the endpoints, which makes the boundary form vanish directly. The inner product used here is the ordinary integral; the weight enters the generalized eigenvalue problem, not this boundary-form calculation.
Apply the identity from (c) to the two real eigenfunctions. The equations of their Sturm-Liouville problem giveSince the eigenvalues differ,This is orthogonality in the weighted inner product.
For an admissible nonzero real trial function, integration by parts and the zero-flux boundary conditions reduce the Rayleigh quotient toA nonzero constant trial function attains zero. Positivity of also shows that equality requires . HenceIf the conserved total amount is , the normalized stationary solution isIts diffusive flux vanishes everywhere. The Boltzmann distribution fixes the spatial profile, while the diffusivity affects the relaxation toward it. Boundedness of makes the normalization finite on this finite interval.
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