As an estimate, model the confinement by an infinite square well of width and use the stipulated electron mass. Its energy eigenvalues are , , so the gap controlling thermal occupation of a quantum well isThus suppresses excitation: . For example makes this ratio below one percent in this model. There is no sharp cutoff. The ground state energy itself corresponds to about , but it is the excitation gap that enters the Boltzmann factor. Finite barrier height and a different effective mass would change the numerical scale; neither is supplied.
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