Inverting the definitions of the creation operator and annihilation operator gives . Their actions and the orthogonality of the oscillator energy eigenstates giveThus the electric dipole transition selection rule iswith the lower alternative absent for . The field exchanges one oscillator quantum in first-order dipole coupling. For a long weak monochromatic drive, its frequency must also be resonant with the level separation, here , to give a substantial transition probability. Higher-order multiphoton processes are beyond the stated single-position-matrix element approximation.
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