Let and , so and . The canonical commutation relation givesHence . Similarly,Using the product rule for a commutator, , givesThus is the number operator, while and are the annihilation operator and creation operator.
The commutators implyThus any nonzero resulting vector is the adjacent energy eigenstate. Since and , their squared norms areChoosing consistent phases for the eigenstates yieldsThe vanishing last expression terminates the lowering sequence at the ground state, rather than introducing a negative-energy oscillator state.
In the position representation , so becomesIntegrating and using the Gaussian integral for wavefunction normalization givesThe creation operator gives , and thereforeIts norm is one since . Moreover is even and is odd, so the overlap integrand is odd and integrable. Integration over the whole real line gives , establishing orthogonality.
Inverting the definitions of the creation operator and annihilation operator gives . Their actions and the orthogonality of the oscillator energy eigenstates giveThus the electric dipole transition selection rule iswith the lower alternative absent for . The field exchanges one oscillator quantum in first-order dipole coupling. For a long weak monochromatic drive, its frequency must also be resonant with the level separation, here , to give a substantial transition probability. Higher-order multiphoton processes are beyond the stated single-position-matrix element approximation.
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