Past exam of the physics B course of the University of Cambridge / 2018 / Paper 2 / Section A / A4 / Solution

Model air as a dilute ideal gas of molecules described by the hard sphere model. The number density and mean free path areThe factor $\sqrt{2}$ accounts for the relative motion of the colliding molecules. A molecular collision diameter has to be estimated because none is supplied. Taking $d\simeq 0.37\mathrm{nm}$, appropriate as an order-of-magnitude size for the main constituents of air, givesThus the mean free path is about $7\times 10^{-8}\mathrm{m}$, or $70\mathrm{nm}$. A slightly smaller assumed diameter $0.35\mathrm{nm}$ gives about $76\mathrm{nm}$, illustrating the intended precision of the estimate.