Past exam of the physics B course of the University of Cambridge / 2022 / Paper 2 / Section A / A5 / Solution

Let $N_u,N_l$ be the upper- and lower-level populations and $g_u,g_l$ their degeneracy factors. At thermal equilibrium, the Boltzmann distribution givesNo degeneracy factors are supplied, so the numerical answers use equal degeneracy factors. Stating the ratio as upper population divided by lower population removes an otherwise arbitrary inversion.

(a) At $T=500\mathrm{K}$,The two populations are nearly equal because the level separation is much smaller than the thermal energy $k_{B}T$.

(b) At $T=2\mathrm{mK}=0.002\mathrm{K}$,Almost every atom occupies the lower level. If the levels have unequal degeneracy factors, each boxed ratio must be multiplied by $g_u/g_l$; their individual values cannot be inferred from the paper.