Put . In the long-wavelength limit , the Taylor expansion in Planck's law gives the Rayleigh-Jeans law,This is the classical equipartition theorem result: each electromagnetic mode carries mean energy . Extending it to arbitrarily high frequency would make the total energy density diverge, the ultraviolet catastrophe.
In the short-wavelength limit , , giving the Wien approximation,Large photon energies are thermally suppressed, removing the classical high-frequency divergence.
If the requested “form” is expressed per unit wavelength, the change of variables includes its Jacobian determinant: . ThusSubstituting without the Jacobian determinant would give an incorrect spectral density.
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