Past exam of the short options paper of the physics Prelims of the University of Oxford / 2021 / S03 / 1 / c / Solution

Put $x=h\nu /(k_{B}T)=hc/(\lambda k_{B}T)$. In the long-wavelength limit $x\ll 1$, the Taylor expansion $e^x-1=x+O(x^2)$ in Planck's law gives the Rayleigh-Jeans law,This is the classical equipartition theorem result: each electromagnetic mode carries mean energy $k_{B}T$. Extending it to arbitrarily high frequency would make the total energy density diverge, the ultraviolet catastrophe.

In the short-wavelength limit $x\gg 1$, $e^x-1\simeq e^x$, giving the Wien approximation,Large photon energies are thermally suppressed, removing the classical high-frequency divergence.

If the requested “form” is expressed per unit wavelength, the change of variables includes its Jacobian determinant: $U_{\lambda }=U_{\nu }|d\nu /d\lambda |=U_{\nu }c/{\lambda }^2$. ThusSubstituting $\nu =c/\lambda$ without the Jacobian determinant would give an incorrect spectral density.