Black-body radiation and the photoelectric effect exposed failures of classical continuous-wave energy exchange. Classical equipartition predicted an unbounded short-wavelength thermal spectrum, the ultraviolet catastrophe. Quantized oscillator energies En=nhν give the mean excitation energy hν/(ehν/(kBT)−1) and suppress high-frequency modes, producing Planck's law. In the modern description, thermal radiation consists of photons with energy hν and Bose occupation numbers.
For the photoelectric effect, increasing intensity below a threshold frequency does not eject electrons, whereas the maximum electron kinetic energy grows with frequency above threshold. Absorption of one photon transfers hν to one electron, giving Kmax=hν−W and threshold ν0=W/h, where W is the work function. Intensity primarily changes the photon arrival rate and hence the photocurrent in the ordinary single-photon regime. Thus changing energy per quantum and changing the number of quanta have distinct consequences. Historically the thermal derivation first quantized matter's energy exchange; it should not be described as an already complete derivation of modern photon theory.
For a photon, pγ=E/c and λγ=hc/E. The neutron is nonrelativistic here because 18.8keV≪mnc2, so pn=2mnE and λn=h/pn. Using the supplied common energy givesEqual kinetic energies do not imply equal momenta: the massive particle obeys E=p2/(2mn), while the massless photon obeys E=pc. The neutron momentum is about 316 times larger, so its de Broglie wavelength is about 316 times smaller.
pγ=1.005×10−23kgms−1,λγ=6.595×10−11m,
pn=3.176×10−21kgms−1,λn=2.086×10−13m.
To give the neutron the photon wavelength, set its momentum to E/c, not its kinetic energy to E again. ThenIts kinetic energy would then be about 0.188eV, connecting this comparison with the next calculation.
vn≃mncE=5.999×103ms−1.
For a transverse periodic row of scatterers of spacing d, normal incidence makes their incident phases equal. Scattering at angle θ from that normal creates an outgoing path difference dsinθ between neighbours. Constructive interference requires a phase difference 2πn, givingUsing this printed relation as the intended transverse diffraction grating model, the nonrelativistic neutron wavelength at 0.188eV is λ=6.5964×10−11m. Hence the first-order data giveGeometry qualification: this is not a derivation from reflection at crystal planes parallel to the surface, as the source prose says. The ordinary Bragg's law for planes of normal separation d is 2dsinθB=nλ, where θB is the incident glancing angle to those planes. At normal incidence on parallel planes, θB=π/2 and specular reflected rays leave along the normal, so their angle from the normal is zero; they cannot obey the printed positive-order relation dsin0=nλ for λ>0. This is a concrete counterexample to identifying the two geometries. The numerical spacing above is therefore conditional on the printed grating-like relation, rather than a forced assertion that the stated Bragg geometry proves it.
dsinθ=nλ.
d=sin(0.117)λ=5.651×10−10m.
For nonrelativistic neutrons, λ∝EK−1/2, so first-order uncertainty propagation gives ∣Δλ∣/λ=21∣ΔEK∣/EK=0.05. ThusAt fixed d, differentiating the stipulated first-order relation dsinθ=λ gives Δθ=tanθΔλ/λ. ConsequentlyFor photons, λ∝E−1, so the same fractional energy uncertainty gives Δλγ/λγ=0.10. Their 18.8keV wavelength almost equals the low-energy neutron wavelength, so the conditional central angle is 0.116973rad andabout twice the neutron angular spread. This difference comes from the different energy-momentum relations, not from substantially different central wavelengths. The small-angle approximation is adequate at 0.117rad: replacing sinθ by θ changes it by about θ2/6=0.23%, and replacing tanθ by θ changes the sensitivity by about 0.46%. The numerical angular results retain the preceding geometry qualification; a different physical scattering geometry would require its own angle convention.
Δλn≃3.30×10−12m.
Δθn≃0.00588rad.
Δθγ≃0.01175rad,
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