Black-body radiation and the photoelectric effect exposed failures of classical continuous-wave energy exchange. Classical equipartition predicted an unbounded short-wavelength thermal spectrum, the ultraviolet catastrophe. Quantized oscillator energies give the mean excitation energy and suppress high-frequency modes, producing Planck's law. In the modern description, thermal radiation consists of photons with energy and Bose occupation numbers.
For the photoelectric effect, increasing intensity below a threshold frequency does not eject electrons, whereas the maximum electron kinetic energy grows with frequency above threshold. Absorption of one photon transfers to one electron, giving and threshold , where is the work function. Intensity primarily changes the photon arrival rate and hence the photocurrent in the ordinary single-photon regime. Thus changing energy per quantum and changing the number of quanta have distinct consequences. Historically the thermal derivation first quantized matter's energy exchange; it should not be described as an already complete derivation of modern photon theory.
For a photon, and . The neutron is nonrelativistic here because , so and . Using the supplied common energy gives
Equal kinetic energies do not imply equal momenta: the massive particle obeys , while the massless photon obeys . The neutron momentum is about times larger, so its de Broglie wavelength is about times smaller.
To give the neutron the photon wavelength, set its momentum to , not its kinetic energy to again. Then
Its kinetic energy would then be about , connecting this comparison with the next calculation.
For a transverse periodic row of scatterers of spacing , normal incidence makes their incident phases equal. Scattering at angle from that normal creates an outgoing path difference between neighbours. Constructive interference requires a phase difference , giving
Using this printed relation as the intended transverse diffraction grating model, the nonrelativistic neutron wavelength at is . Hence the first-order data give
Geometry qualification: this is not a derivation from reflection at crystal planes parallel to the surface, as the source prose says. The ordinary Bragg's law for planes of normal separation is , where is the incident glancing angle to those planes. At normal incidence on parallel planes, and specular reflected rays leave along the normal, so their angle from the normal is zero; they cannot obey the printed positive-order relation for . This is a concrete counterexample to identifying the two geometries. The numerical spacing above is therefore conditional on the printed grating-like relation, rather than a forced assertion that the stated Bragg geometry proves it.
For nonrelativistic neutrons, , so first-order uncertainty propagation gives . Thus
At fixed , differentiating the stipulated first-order relation gives . Consequently
For photons, , so the same fractional energy uncertainty gives . Their wavelength almost equals the low-energy neutron wavelength, so the conditional central angle is and
about twice the neutron angular spread. This difference comes from the different energy-momentum relations, not from substantially different central wavelengths. The small-angle approximation is adequate at : replacing by changes it by about , and replacing by changes the sensitivity by about . The numerical angular results retain the preceding geometry qualification; a different physical scattering geometry would require its own angle convention.

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