The canonical momentum is pi=∂L/∂q˙i. If the velocity-momentum relation can be locally inverted, the Legendre transform defines H(q,p,t)=∑ipiq˙i−L, with the velocities expressed in terms of q,p,t. Its differential isThe Euler-Lagrange equations then yield Hamilton's equations,A singular velocity Hessian instead requires a constrained-Hamiltonian treatment.
dH=∑iq˙idpi−∑i∂qi∂Ldqi−∂t∂Ldt.
q˙i=∂pi∂H,p˙i=−∂qi∂H.
The canonical momentum is p=γmr˙, where γ=(1−r˙2/c2)−1/2. Eliminating velocity givesIts Hamilton equations are r˙=c2p/H and p˙=0. In the limit ∣p∣≪mc, the Taylor expansion is H=mc2+p2/(2m)+O(p4/(m3c2)), and r˙≃p/m. The additive rest energy does not change the classical free-particle equations.
H=γmc2=m2c4+c2p2.
Minimal electromagnetic coupling changes the canonical momentum to p=γmr˙+qA. The mechanical momentum is π=p−qA. The Legendre transform yieldsThe cancellation of qr˙⋅A in the Legendre transform does not remove magnetic effects: A remains in the relation between canonical and mechanical momenta. The expression is the relativistic kinetic-plus-rest energy with an electrostatic potential-energy term, expressed in canonical variables.
H(r,p,t)=m2c4+c2[p−qA(r,t)]2+qϕ(r,t).
Let E=m2c4+c2π2. Hamilton's equations giveSubtracting qdAi/dt from the second equation gives the familiar Lorentz force, π˙=q(E+r˙×B), with E=−∇ϕ−∂tA and B=∇×A. This also checks the signs of both potential terms.
r˙i=Ec2πi,p˙i=qj∑r˙j∂iAj−q∂iϕ.
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