Let x<=min(x,x′) and x>=max(x,x′). A homogeneous solution vanishing at the left wall is u(x)=sin[k(x+a/2)]; one vanishing at the right wall is v(x)=sin[k(a/2−x)]. Their Wronskian is uv′−u′v=−ksinka. Continuity and the source derivative jump G+′−G−′=−2m/ℏ2 therefore giveThis is exactly the printed form because x<=(x+x′−∣x−x′∣)/2 and x>=(x+x′+∣x−x′∣)/2, with a minus sign from reversing the argument of the second sine.
G(x,x′)=kℏ2sinka2msin[k(x<+a/2)]sin[k(a/2−x>)].
The true poles occur at kn=nπ/a, n=1,2,…, corresponding toThe apparent zero at k=0 is removable: the numerator and ksinka both vanish quadratically. Negative values of kn duplicate the same energies, rather than describing extra levels. The boundary conditions and source jump uniquely determine the inverse whenever E is not an eigenvalue.
En=2ma2ℏ2π2n2.
Expand G(x,x′) in a complete orthonormal eigenbasis in its first argument. Applying the operator yields ∑n(En−E)cnφn(x)=δ(x−x′). Completeness expands the Dirac delta distribution as ∑nφn(x)φn∗(x′), soConsequently limE→En(En−E)G=φn(x)φn∗(x′).
cn=En−Eφn∗(x′),G(x,x′)=n∑En−Eφn(x)φn∗(x′).
For the explicit formula, use En−E≃−(ℏ2kn/m)(k−kn) and sinka≃(−1)na(k−kn). Also
sin[kn(a/2−x)]=(−1)n+1sin[kn(x+a/2)]. The resulting limit isThe expression is symmetric in x,x′ and holds on either side of the source. The usual complex-analysis residue with respect to E−En has the opposite sign, since the source requests the limit with En−E.
sin[kn(a/2−x)]=(−1)n+1sin[kn(x+a/2)]. The resulting limit is
φn(x)φn∗(x′)=a2sinanπ(x+a/2)sinanπ(x′+a/2).
Factorizing the projector found in part b gives the normalized eigenfunctionswith zero continuation outside. Their squared integrals are one and different positive integers give orthogonal functions. These are the familiar infinite-square-well states shifted so that the well centre is at zero. Each eigenfunction has an arbitrary overall constant phase, which cancels from the projector.
φn(x)=a2sinanπ(x+a/2),−a/2<x<a/2,n≥1,
For E<0, inversion of the free operator gives G0(x,y)=me−κ∣x−y∣/(κℏ2), with κ=−2mE/ℏ. The bound-state equation is ψ=−G0Uψ, henceFor the separable kernel V(y,z)=−αF(y)F∗(z), defineThenAn overall normalization still has to be chosen after finding a permitted energy. A nontrivial bound state must have C=0: if C=0, the potential acts as zero and a square-integrable negative-energy free solution on the whole line cannot exist. Decay or square-integrability assumptions on F are needed to make these integrals well defined; smoothness alone would not ensure convergence.
ψ(x)=−κℏ2m∫∫e−κ∣x−y∣V(y,z)ψ(z)dydz.
C=∫−∞∞F∗(z)ψ(z)dz.
ψ(x)=κℏ2αmC∫e−κ∣x−y∣F(y)dy.
Multiply the expression for ψ by F∗(x) and integrate. Cancelling the nonzero C givesThe kernel is real and symmetric, so relabelling the integration variables puts the expression in the printed order:This is the scalar consistency condition for the rank-one potential, rather than an independent normalization equation. The double integral is real and nonnegative because the Fourier transform of e−κ∣x∣ is 2κ/(q2+κ2)>0. Thus attractive α>0 is needed for a nontrivial solution. Under the usual integrability assumptions the corresponding free resolvent expectation decreases with κ, giving at most one bound state for this rank-one attraction.
1=κℏ2αm∫∫F∗(x)F(y)e−κ∣x−y∣dxdy.
κ=ℏ2αm∫∫F(x)F∗(y)e−κ∣x−y∣dxdy,E=−2mℏ2κ2,κ>0.
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