Quantum tunnelling is transmission through a region where the particle's energy is below the classical potential energy. The stationary wavefunction decays within that region but need not vanish at its far boundary, so matching can leave a nonzero transmitted probability current.
This does not require a particle to borrow energy temporarily. Energy is conserved for a time-independent barrier; the classically forbidden region is described by an evanescent wave, with the same stationary energy as the incident and transmitted waves.
Inside a rectangular barrier with , the stationary Schrödinger equation gives
Its independent solutions are with
For an opaque barrier the amplitude is suppressed by approximately and the probability by . Matching contributes a prefactor, so this exponential approximation is not an exact transmission coefficient for a transparent or very thin barrier. For two moving particles the relative-coordinate mass is their reduced mass.
At a separation of fm, the proton Coulomb energy is approximately MeV, whereas keV at the stated solar-core temperature. As a deliberately crude rectangular-barrier estimate, take a width of fm and use the two-proton reduced mass . Then
so
Treating one proton as fixed and using instead gives about . Both estimates only say that this arbitrarily shortened barrier would be fairly transparent; the opaque-barrier exponential is itself uncontrolled for such a small exponent.
There is an important conditioning issue. If the protons have already reached a separation of one femtometre, most of the long-range Coulomb suppression has already been overcome. The rectangular estimate cannot represent the probability for thermal protons starting far apart. Their classical turning separation at this energy is about fm, not one femtometre.
Two major suppressions are missing from the one-femtometre rectangular estimate. First, the Coulomb barrier extends far beyond nuclear distances and is not rectangular. A semiclassical integral through it produces the Gamow factor , with ; at the illustrative thermal energy it is already of order . A thermal average additionally weights the high-energy tail and is not the same as evaluating a single thermal energy.
Second, two protons cannot simply form a stable bound diproton. The proton–proton chain starts with a weak-interaction conversion producing a deuteron, a Positron and a neutrino. The weak transition probability supplies a further very large suppression. Thus the quoted tiny fusion probability is not a pure one-dimensional barrier transmission probability with universal energy-independent meaning.
The Sun contains of order nucleons in a hot dense core and offers enormously many encounters over astronomical times. A very small reaction probability per encounter can therefore supply its luminosity while consuming only a small fraction of the fuel per unit time. The small weak reaction rate is also crucial for the long stellar lifetime; a larger core temperature increases burning and triggers expansion and cooling.

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