A quantum state ensemble of normalized states , with probabilities and , has density operatorIt is a positive semidefinite Hermitian operator with trace one, and the Born rule assigns a measurement outcome with projector the probability .
A pure state has , hence and purity of a density operator . Its only nonzero eigenvalue is one. A mixed state has at least two nonzero eigenvalues and . The spectral theorem proves the converse criteria, since the nonnegative eigenvalues sum to one. Different quantum state ensembles may give the same density operator; the mere presence of several terms in a preparation list does not make the state mixed if all positive-weight terms represent the same quantum state ray.
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