A quantum state ray is the equivalence class of nonzero vectors in a complex Hilbert space under multiplication by a nonzero complex number. Its span is a one-dimensional linear subspace, but the zero vector is not a state representative. A unit vector fixes the norm and leaves a global phase free. [ref]
Foundations I: States and Ensembles by John Preskill. Preskill, Foundations I: States and Ensembles, §2.1, printed p. 2, ray equivalence and normalized representatives
For a nonzero representative , the associated pure state density operator isReplacing by multiplies both numerator and denominator by , so the quotient is unchanged. In particular, for every POVM effect ,This proves that a global phase changes no measurement probability. Changing the relative quantum phase of two nonzero components can change the density operator, as the following comparison shows.
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