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Use $g_{\mu \nu }=\mathrm{diag}(1,-1,-1,-1)$ throughout. Vary the Maxwell action with respect to the electromagnetic four-potential. Antisymmetry of the electromagnetic field tensor gives $\delta \mathcal{L}=-F^{\mu \nu }{\partial }_{\mu }\delta A_{\nu }$. After integration by parts, the Euler-Lagrange field equation isA gauge transformation $A_{\mu }\mapsto A_{\mu }+{\partial }_{\mu }\chi$ leaves $F_{\mu \nu }$ unchanged because partial derivatives commute. It therefore leaves the Maxwell action and observable electromagnetic fields unchanged: different potentials represent the same physical field. This redundancy matters for canonical quantization: before gauge fixing, the momentum conjugate to $A_0$ vanishes and the four potential components cannot be treated as four independent physical oscillators.

Choose the Lorenz gauge $D={\partial }_{\mu }{A}^{\mu }=0$, attainable by solving $\square \chi =-D$ with suitable boundary data. The Euler-Lagrange field equation then reduces toResidual Lorenz gauge symmetry consists of transformations with $\square \chi =0$. The gauge condition and this residual redundancy ultimately leave two transverse polarizations of a free photon.

For the specified kinetic density ${\mathcal{L}}_C=-\frac{1}{2}{\partial }_{\mu }{A}_{\nu }{\partial }^{\mu }{A}^{\nu }$, one has $\partial {\mathcal{L}}_C/\partial ({\partial }_{\mu }{A}_{\nu })=-{\partial }^{\mu }{A}^{\nu }$. Its Euler-Lagrange field equation is therefore $-\square A^{\nu }=0$. This density is the Feynman-gauge Maxwell kinetic density after a boundary-term subtraction, sinceThe divergence follows by expanding both sides and commuting the second derivatives. Thus the wave equation follows from a Feynman gauge action; the additional physical-state condition will implement the Lorenz gauge. One must not impose $D=0$ inside the original action before varying it.

Take the covariant components $A_{\nu }$ as canonical coordinates. The canonical momentum computed from ${\mathcal{L}}_C$ isThe equal-time canonical Poisson brackets are $\{A_{\mu }(t,\mathbf{x}),{\Pi }^{\nu }(t,\mathbf{y})\}={\delta }_{\mu }{}^{\nu }{\delta }^3(\mathbf{x}-\mathbf{y})$, with coordinate-coordinate and momentum-momentum brackets zero. Applying canonical quantization givesIn particular $[A_{\mu },{\dot{A}}_{\nu }]=-i{g}_{\mu \nu }{\delta }^3$. The negative temporal sign is the source of the indefinite state-space norm in covariant photon quantization.

The spatial Fourier transform of the wave equation gives an oscillator of frequency $\omega =|\mathbf{k}|$ for each component. The Hermitian adjoint condition on the electromagnetic four-potential then yields the mode expansion of a free fieldThese are massless on shell modes. Consistently with the preceding equal-time canonical commutation relation,The normalization is the same as for the scalar modes, with $-g_{\mu \nu }$ replacing the species identity matrix.

Gupta-Bleuler quantization starts with the Fock vacuum annihilated by every $a_{\mu }$ and imposes only the annihilation, or positive-frequency part of a quantum field, of the Lorenz gauge condition:Imposing the entire Hermitian field divergence as a strong operator identity would be incompatible with the four-component canonical commutation relation. The weaker condition suffices: between two physical states its positive-frequency part vanishes on the ket, and its negative-frequency part vanishes on the bra. Hence $⟨{\mathrm{phys}}^{\prime }|{\partial }_{\mu }{A}^{\mu }|\mathrm{phys}⟩=0$.

For a one-photon state $|\mathbf{k},ϵ⟩={ϵ}^{\nu }{a}_{\nu }^{†}(\mathbf{k})|0⟩$, commuting the constraint through the creator givesThus the allowed photon polarization vectors satisfy $\boxed{k\cdot ϵ=0}$. Their state inner product, with the common momentum-normalization factor suppressed, is $⟨{ϵ}^{\prime }|ϵ⟩=-{ϵ}^{\prime \ast }\cdot ϵ$. Momentum eigenstates are delta-normalized; the same statements hold with finite norms for normalizable wave packets.

Rotate the spatial axes so that $k=\omega (1,0,0,1)$. The constraint is ${ϵ}^0={ϵ}^3$, so the complete allowed family isThe first vector is the allowed longitudinal gauge polarization, proportional to the null four-momentum $k$. Its state has zero norm because $k^2=0$; it is also orthogonal to every constrained state because $k\cdot ϵ=0$. A purely spatial vector $(0,0,0,1)$ alone is not an allowed physical polarization: its time component must accompany it to satisfy the constraint. The other two vectors are transverse polarizations, perpendicular to $\mathbf{k}$, with positive unit norms. For the displayed family,The timelike negative-norm excitation has been excluded by the constraint, and the remaining form is positive semidefinite. The Gupta-Bleuler null-state quotient identifies $ϵ$ and $ϵ+\lambda k$, removing the null direction. It leaves exactly two transverse physical photon polarizations with a positive inner product; their bosonic Fock space is the physical photon state space.

Finally use Feynman slash notation, $/a={\gamma }^{\mu }{a}_{\mu }$, and impose four-momentum conservation $p+q=k+k^{\prime }$. The external Dirac spinors obeySet $r=p-k$ and $r^{\prime }=p-k^{\prime }$. Replacing $ϵ$ by $k$ in the first term of the electron-positron annihilation into two photons amplitude, the rightmost contracted vertex obeysSince the Clifford algebra implies $(/r+m)(/r-m)=(r^2-m^2)I_4$, that term becomesFor the second term, four-momentum conservation gives $k=q+r^{\prime }$. The contracted vertex is now adjacent to the outgoing positron spinor on the left, soConsequentlyThe two terms cancel, proving the two-photon fermion Ward identityExchanging the two photon labels proves the same result for ${ϵ}^{\prime }=k^{\prime }$. By linearity the amplitude is invariant under $ϵ\mapsto ϵ+\lambda k$ on either external photon leg. Therefore the null longitudinal gauge polarization has zero production amplitude: physical scattering produces only the two transverse photon polarizations. This cancellation also shows why both photon orderings in the tree-level Feynman diagrams are essential; either term alone fails the Ward identity.

The oscillator commutator givesThe temporal mode $\lambda =0$ has negative norm. More precisely, the nonzero wave packet $|f,0⟩=\int d^{3}pf(\mathbf{p})a_{\mathbf{p}}^{0†}|0⟩/(2\pi {)}^3$ has norm $-\int d^{3}p|f(\mathbf{p}){|}^2/(2\pi {)}^3<0$. The difficulty is an indefinite Hermitian form, not the divergent normalization of an unsmeared momentum eigenstate. The covariant photon Fock space is therefore not a positive physical Hilbert space.

Gupta-Bleuler quantization imposes only the annihilation, or positive-frequency part of a quantum field, of the divergence:A strong operator identity $\partial \cdot A=0$ is incompatible with the four unconstrained canonical commutation relations; in the literal momentum convention it would set ${\pi }^0=0$. The weaker condition instead implies $⟨\Phi |\partial \cdot A|\Psi ⟩=0$ between physical states: the positive-frequency part annihilates the ket, and its adjoint annihilates the bra.

For a nonzero momentum choose upper-index polarization vectorswhere ${\mathbf{e}}_1,{\mathbf{e}}_2$ are an orthonormal pair perpendicular to $\mathbf{p}$. Labels 1 and 2 have transverse polarization, label 3 has spatial longitudinal polarization, and label 0 has timelike photon polarization. With $p^0=|\mathbf{p}|=\omega$, the divergence of the annihilation part is proportional to $-i\omega (a_{\mathbf{p}}^0-a_{\mathbf{p}}^3)$. The physical condition is thereforeFor a one-mode state $|\chi ⟩={\sum }_{\lambda }{c}_{\lambda }{a}^{\lambda †}|0⟩$, the condition reads $-c_0-c_3=0$. ThusThe last direction has zero norm and is orthogonal to every constrained state. Its field wavefunction is proportional to ${ϵ}^{\mu 0}+{ϵ}^{\mu 3}=p^{\mu }/\omega$, hence it is a pure gauge symmetry direction. A purely longitudinal creator $a^{3†}$ alone is not physical, despite having positive norm.

For the multiparticle sketch, put $C=a^0-a^3$ and $C^{†}=a^{0†}-a^{3†}$. The commutator $[C,C^{†}]=0$ allows polynomials in $C^{†}$ times transverse creator states to obey the constraint. Conversely, on creator polynomials the constraint is $-{\partial }_{a^{0†}}-{\partial }_{a^{3†}}$, so these are all the constrained polynomials. Every term containing $C^{†}$ is orthogonal to every constrained bra, since $⟨\Phi |C^{†}=⟨C\Phi |=0$. Quotienting those null vectors and completing the remaining positive space is the Gupta-Bleuler null-state quotient. It givesThe one-particle instance is the transverse one-photon physical quotient.

Use ${\eta }_{\mu \nu }=\mathrm{diag}(1,-1,-1,-1)$ and $\hslash =c=1$. In the interaction picture, fields evolve with the free Hamiltonian, while interactions enter the state evolution through the Dyson series. Write the Klein-Gordon field as $\varphi ={\varphi }^{(+)}+{\varphi }^{(-)}$, with the positive-frequency part of a quantum field containing annihilation operators and ${\varphi }^{(-)}=({\varphi }^{(+)}{)}^{†}$ containing creation operators. The mode normalization in the PDF corresponds to $[a_{\mathbf{p}},a_{\mathbf{q}}^{†}]=(2\pi {)}^3{\delta }^3(\mathbf{p}-\mathbf{q})$ and $E_{\mathbf{p}}=\sqrt{|\mathbf{p}{|}^2+m^2}$.

The time-ordered product places fields with the latest time on the left. For two bosonic insertions,The normal-ordered product $:\varphi (x_1)\cdots \varphi (x_n):$ instead moves every creation operator to the left of every annihilation operator, without adding the commutators generated by that rearrangement. Its vacuum expectation value is zero whenever a nonempty set of free-field factors remains.

The mode commutator gives the positive-frequency Wightman functionDefine the Feynman propagator here to be the two-point function itself, rather than that function divided by $i$. ThenEquivalently,The positive-energy pole is below and the negative-energy pole above the real axis. Closing the energy contour integral below for positive time separation and above for negative time separation gives the two terms above. Thus this is the scalar Feynman propagator pole prescription, and $(\square +m^2){\Delta }_F=-i{\delta }^4$. In particular, $T\{\varphi (x)\varphi (y)\}=:\varphi (x)\varphi (y):+{\Delta }_F(x-y)$: the difference between time ordering and normal ordering is the Wick contraction.

For $n$ free bosonic fields, the Wick theorem stateswhere $P$ runs over all sets of disjoint pairs of indices, including the empty set, and $V(P)$ is the set of paired indices. The empty normal-ordered product equals one. This is an operator identity for free fields, understood with smearing or a regulator when products of operator-valued distributions require it.

Here is an inductive proof of the scalar Wick theorem. Sort the arguments chronologically so that $x_1^0$ is the latest. For any remaining set $I$, commuting the annihilation part of ${\varphi }_1$ through the creation parts in a normal-ordered product givesThe creation part of ${\varphi }_1$ is already in the correct position. Every commutator on the right is a scalar, so no further operator rearrangement is needed for it. Because $x_1$ is latest, that commutator is ${\Delta }_F(x_1-x_j)$. Assume the Wick theorem for the other $n-1$ fields and multiply its expansion by ${\varphi }_1$. The first term of the displayed identity gives every pairing in which index 1 is unpaired; the sum gives every pairing in which 1 is paired with exactly one $j$. Each final partial pairing has exactly one such construction. The one-field identity supplies the base case, proving the theorem by mathematical induction. Applying time ordering restores arbitrary argument order.

Taking the vacuum expectation value retains only complete pairings. Odd free correlators vanish; for example the free scalar four-point function is ${\Delta }_{12}{\Delta }_{34}+{\Delta }_{13}{\Delta }_{24}+{\Delta }_{14}{\Delta }_{23}$. These facts explain why propagators are the edges of Feynman diagrams.

For the interacting quartic scalar field theory, the interaction Hamiltonian density is $\lambda {\varphi }^4/4!$. With a single time ordering acting on external insertions and interaction vertices, the unnormalized numerator expands asApply the proved Wick theorem term by term. Each complete pairing connects external insertions and four-legged vertices by Feynman propagators. There are $4!$ assignments of four distinct incident legs at a vertex, canceling its factorial. Permuting identical integrated vertices cancels the corresponding part of $v!$. Permutations still leaving the labeled graph unchanged give its Feynman-diagram symmetry factor. For example,whereas the two-point tadpole diagram has coefficient $-i\lambda /2$, because choosing the two vertex legs contracted with the labeled external fields gives $4\cdot 3$ possibilities and the other two contract with each other.

Thus the position-space rules attach ${\Delta }_F$ to every edge, $-i\lambda \int d^{4}z$ to every four-legged interaction vertex, and divide by the graph's Feynman-diagram symmetry factor. Fourier transformation gives the momentum-space Feynman rules:Enforce momentum conservation at each vertex, retaining the overall four-momentum delta function. External lines of these correlation functions remain unamputated. The unnormalized expression includes Vacuum Feynman diagrams; dividing by $N_0=⟨0|S|0⟩$ cancels those disconnected vacuum factors. They should not be discarded without that normalization.

There is a time-ordering convention in the printed correlation-function notation worth making explicit. The usual interacting correlator uses the single global time ordering in $N_n$ above. If the displayed $T\{{\varphi }_1\cdots {\varphi }_n\}S$ is read literally with $S$ outside that ordering, the external block and the vertex block are separately time ordered: their cross-contractions are $D^{+}(x_i-z)$ because each external field stands to the left of every vertex field. The same pairing construction then uses ${\Delta }_F$ for lines within either block and $D^{+}$ for lines between blocks; in momentum space the latter is $2\pi \theta (p^0)\delta (p^2-m^2)$. This literal product is different from the conventional globally time-ordered interacting correlator, and does not have the ordinary external Feynman propagators derived above.

The oscillator-generated covariant photon Fock space has an indefinite Hermitian form, not a positive Hilbert space inner product. For a normalizable one-photon wave packet of polarization $\lambda$, its squared norm is proportional to $-{\eta }^{\lambda \lambda }\int d^{3}p|f(\mathbf{p}){|}^2$. Thus $\lambda =0$ gives a negative-norm photon state. The divergent ${\delta }^3(0)$ of an unsmeared momentum eigenstate is a separate normalization issue, avoided by the wave packet.

Choose contravariant polarization vectors ${ϵ}^{0\mu }=(1,0)$, ${ϵ}^{3\mu }=(0,\hat{\mathbf{p}})$, and two ${ϵ}^{r\mu }=(0,{\mathbf{e}}_r)$ with ${\mathbf{e}}_r\cdot \mathbf{p}=0$ for $r=1,2$. The third spatial polarization is longitudinal polarization; the first two are transverse polarization. The timelike photon polarization is distinct from the longitudinal one.

The Gupta-Bleuler quantization condition sets the divergence of the positive-frequency part of a quantum field to zero on physical states:Restore the factors $e^{-i|\mathbf{p}|t}$ to the annihilation terms. Since $p_{\mu }{ϵ}^{0\mu }=|\mathbf{p}|$ and $p_{\mu }{ϵ}^{3\mu }=-|\mathbf{p}|$, Fourier transform gives the equivalent conditionIts sign depends on the chosen sign of the longitudinal polarization vector; the covariant condition does not.

To see its content for a general Fock state, temporarily discretize momentum and decompose one unphysical oscillator sector as $|\Psi ⟩={\sum }_{n,m\ge 0}|n,m{⟩}_{0,3}\otimes |{\chi }_{nm}{⟩}_{\perp }$, where $|n,m⟩=(a^{0†}{)}^n(a^{3†}{)}^m|0⟩/\sqrt{n!m!}$. The temporal oscillator obeys $a^0|n,m⟩=-\sqrt{n}|n-1,m⟩$, while $a^3|n,m⟩=\sqrt{m}|n,m-1⟩$. The condition therefore becomesEquivalently, the allowed finite-particle states use the transverse creation operators and only $b^{†}=a^{0†}-a^{3†}$ in the unphysical sector. Indeed the constraint acts on a polynomial of the two unphysical creation operators as $-{\partial }_{a^{0†}}-{\partial }_{a^{3†}}$, whose kernel consists of polynomials in their difference. Also $[b,b^{†}]=-1+1=0$, and a state containing $b^{†}$ is orthogonal to every constrained state because $b$ annihilates every such state. This argument applies mode by mode and extends by smearing to continuum momentum.

For one photon, $c_0{a}^{0†}|0⟩+c_3{a}^{3†}|0⟩$ is constrained only when $c_3=-c_0$, producing a null state. The Gupta-Bleuler null-state quotient removes these null directions. The condition excludes negative-norm physical states; quotienting its null states leaves the two positive-norm transverse photon polarizations. The condition alone gives a positive semidefinite Hermitian form, not yet a positive definite Hilbert space.