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For the connected tree scattering amplitude of one particle and one antiparticle of a complex scalar field, the Dyson series inserts $-i\lambda {\varphi }^{†2}{\varphi }^2/4$. There are $2!$ assignments of the particle and antiparticle external attachments to each pair of identical field factors, giving $2!2!=4$ and hence the displayed Feynman vertex. With relativistic normalization of a one-particle state, integrating the vertex position gives $i\mathcal{T}(2\pi {)}^4{\delta }^4(p_1+q_1-p_2-q_2)$ with $\mathcal{T}=-\lambda$. Vacuum diagrams and one-particle self-energy insertions are separate disconnected contributions; normal ordering eliminates the single-vertex vacuum and tadpole contractions.

A one-particle state belongs to the one-excitation sector of a Fock space. In a momentum basis with $[a_{\mathbf{p}},a_{\mathbf{q}}^{†}]=(2\pi {)}^3{\delta }^3(\mathbf{p}-\mathbf{q})$, the wavepacket $\int d^{3}pf(\mathbf{p})a_{\mathbf{p}}^{†}|0⟩/(2\pi {)}^3$ has norm squared $\int d^{3}p|f(\mathbf{p}){|}^2/(2\pi {)}^3$. Sharp-momentum states have distributional rather than unit normalization; factors of $\sqrt{2E_{\mathbf{p}}}$ convert to relativistic normalization of a one-particle state.

Use units $\hslash =c=1$ and the Minkowski metric $g=\mathrm{diag}(1,-1,-1,-1)$. The canonical momentum of the real scalar field is $\pi =\partial \mathcal{L}/\partial \dot{\varphi }=\dot{\varphi }$. Canonical quantization replaces the classical fields by operator-valued distributions and imposes the equal-time canonical commutation relationsThese relations are imposed on an initial slice, with smeared fields understood. In the Heisenberg picture, simultaneous unitary time evolution of both operators preserves their commutators. Since the momentum is $\dot{\varphi }$, the requested equal-time commutator is $[\varphi (t,\mathbf{x}),\dot{\varphi }(t,\mathbf{y})]=i{\delta }^{(3)}(\mathbf{x}-\mathbf{y})$.

The Legendre transform in mechanics, applied pointwise, gives the canonical Hamiltonian density of a real scalar field. ThusTo obtain its dynamics rather than assume them, use the Heisenberg equation of motion $\dot{O}=i[H,O]$. The momentum-square term gives $[H,\varphi ]=-i\pi$. The field-square term gives $[H,\pi ]=i{m}^2\varphi$, while differentiating the Dirac delta function in the gradient term and integrating by parts gives $[H,\pi ]=-i{\nabla }^2\varphi +i{m}^2\varphi$. ConsequentlyBoundary terms vanish for suitably decaying smeared fields. This is the Klein-Gordon equation as an operator identity.

A spatial Fourier transform reduces the Klein-Gordon equation to ${\ddot{\varphi }}_{\mathbf{p}}+E_p^2{\varphi }_{\mathbf{p}}=0$, where $E_p=\sqrt{{\mathbf{p}}^2+m^2}$. Its two frequency branches and the Hermitian adjoint condition giveThe invariant-normalized scalar mode extraction can be written particularly simply asSubstituting the mode expansion of a free field proves these inversion formulas: the opposite-frequency coefficient is proportional to $E_p-E_q$ and vanishes after spatial Fourier inversion. Alternatively they are the corresponding Klein-Gordon inner products. Taking their commutators using the equal-time fields gives $(E_p+E_q)(2\pi {)}^3{\delta }^{(3)}(\mathbf{p}-\mathbf{q})$ in the mixed case. In the two equal-type cases the delta function enforces $\mathbf{q}=-\mathbf{p}$, multiplying $E_p-E_q=0$. ThereforeConversely these mode commutators reproduce $[\varphi ,\dot{\varphi }]=i{\delta }^{(3)}$: the two frequency contributions each supply half the spatial Dirac delta function.

For the covariant oscillator Hamiltonian of a real scalar field, insert the mode expansion of a free field into $H$. Spatial integration sets the two momenta equal in the mixed terms and opposite in the two-creator or two-annihilator terms. The latter have coefficient $-E_p^2+{\mathbf{p}}^2+m^2=0$. The mixed terms giveThe constant $E_0$ is the divergent zero-point energy; a finite box and a momentum cutoff make its meaning explicit. Normal ordering sets the free vacuum energy to zero and leaves all commutators unchanged. Directly applying the mode commutators to the mixed expression yieldsChoose the Fock vacuum by $a(p)|0⟩=0$. Each creation operator adds a boson of energy $E_p$ and four-momentum $p$, while each annihilation operator removes one. Products of commuting creation operators give bosonic statistics from commuting creation operators and unrestricted occupation numbers. The real scalar field has one spin-zero species, identical to its antiparticle. Its one-particle states obey $⟨q|p⟩=(2\pi {)}^{3}2E_p{\delta }^{(3)}(\mathbf{p}-\mathbf{q})$, precisely the relativistic normalization of a one-particle state.

For the Feynman propagator, put $z=x-y$ and contract the two fields in the Fock vacuum. Only $a{a}^{†}$ survives, giving the Wightman functionThe stipulated time-ordered product convention is $i{\Delta }_F(z)=\theta (z^0)W(z)+\theta (-z^0)W(-z)$. In a contour integral over $p^0$, the Feynman i-epsilon prescription places the positive-energy pole just below the real axis and the negative-energy pole just above it. For $z^0>0$ close below, clockwise, obtaining $-i{e}^{-i{E}_p{z}^0}/(2E_p)$; for $z^0<0$ close above, obtaining $-i{e}^{i{E}_p{z}^0}/(2E_p)$. Changing $\mathbf{p}\mapsto -\mathbf{p}$ in the second contribution therefore provesActing with $\square +m^2$ multiplies the integrand by $-(p^2-m^2)$. The remaining factor tends to $-1$ as a distribution, so Fourier inversion givesThe sign also follows from the derivative jump of a free scalar time-ordered two-point function: the first time derivative of $i{\Delta }_F$ jumps by $⟨[\dot{\varphi },\varphi ]⟩=-i{\delta }^{(3)}$, so that of ${\Delta }_F$ jumps by $-{\delta }^{(3)}$.

For the complex scalar field, the canonical momenta are $\pi ={\dot{\varphi }}^{†}$ and ${\pi }^{†}=\dot{\varphi }$. Split $H=H_0+H_I$. The interaction picture is obtained from the Schrödinger picture by $|{\Psi }_I(t)⟩=e^{i{H}_{0}t}|{\Psi }_S(t)⟩$ and $O_I(t)=e^{i{H}_{0}t}{O}_S{e}^{-i{H}_{0}t}$, choosing a common time origin. The fields therefore obey the free Klein-Gordon equation, while the states evolve through $H_I(t)$. The canonical quantization of a complex scalar field givesThe adjoint expansion contains $a^{†}$ and $b$. Particle and antiparticle modes are independent; their nonzero commutators areAll cross-species commutators, and all pairs of creation operators or of annihilation operators, vanish. These formulas reproduce $[\varphi (\mathbf{x}),\pi (\mathbf{y})]=[{\varphi }^{†}(\mathbf{x}),{\pi }^{†}(\mathbf{y})]=i{\delta }^{(3)}(\mathbf{x}-\mathbf{y})$ and the remaining vanishing equal-time commutators.

There are no derivative interactions, so the interaction Hamiltonian is $H_I(t)=-\int d^{3}x{\mathcal{L}}_I(x)$. Differentiating the interaction picture state gives $i{\partial }_t|{\Psi }_I⟩=H_I(t)|{\Psi }_I⟩$. Its time-evolution operator satisfiesIteration gives ordered integration regions $t_1>\cdots >t_n$. Each is $1/n!$ of the full region with a time-ordered product, yielding the Dyson seriesWith the usual asymptotic scattering prescription, taking $t_0\to -\infty$ and $t\to +\infty$ provesTime ordering is essential because different interaction Hamiltonians need not commute.

At first order, use the connected tree scattering amplitude, equivalently the normal-ordered quartic vertex with the vacuum and one-particle mass contributions removed. This qualification matters if the local product is interpreted literally without normal ordering: single-vertex tadpole diagrams and vacuum diagrams are not the requested connected two-particle amplitude. The complex scalar quartic contact vertex is obtained fromIn a fully connected matrix element, an incoming particle and outgoing antiparticle attach to the two $\varphi$ factors; an outgoing particle and incoming antiparticle attach to the two ${\varphi }^{†}$ factors. Each pair has two assignments, giving $2!2!=4$. The external relativistic normalization of a one-particle state cancels each mode measure: for example $[\varphi (x),a^{†}(p_1)]=e^{-i{p}_{1}x}$ and $[b(q_2),\varphi (x)]=e^{i{q}_{2}x}$. Consequently the connected integrand is $4e^{-i(p_1+q_1-p_2-q_2)\cdot x}$, andThus the invariant connected amplitude isThe Dirac delta function expresses four-momentum conservation.

For the identity contribution, commute $a(p_2)$ through $a^{†}(p_1)$ and independently $b(q_2)$ through $b^{†}(q_1)$; all terms leaving a creation operator against the left Fock vacuum or an annihilation operator against the right Fock vacuum vanish. HenceThere is no exchange term between the two distinct particle and antiparticle species.

Use units $\hslash =c=1$ and the Minkowski metric $g_{\mu \nu }=\mathrm{diag}(1,-1,-1,-1)$, so $p\cdot x=E_{p}t-\mathbf{p}\cdot \mathbf{x}$. The canonical momentum of the real scalar field is $\pi =\dot{\varphi }$, and the Hamiltonian operator isCanonical quantization of a real scalar field promotes $\varphi$ and $\pi$ to operator-valued distributions satisfying the equal-time canonical commutation relationProducts and operator commutators can first be interpreted after spatial smearing. An additive vacuum constant in $H$ does not affect the following equations. In the Heisenberg picture, $\dot{O}=i[H,O]$. Applying the canonical commutation relation to the quadratic Hamiltonian operator, and integrating the gradient term by parts, givesThus the Klein-Gordon equation is an operator equation. The spatial Fourier transform reduces it to ${\ddot{\varphi }}_{\mathbf{p}}+E_p^2{\varphi }_{\mathbf{p}}=0$, with $E_p=\sqrt{{\mathbf{p}}^2+m^2}$. Its two frequency branches, together with the Hermitian adjoint condition ${\varphi }^{†}=\varphi$, give the mode expansion of a free fieldThe measure $d\mu (p)$ is Lorentz invariant; its normalization fixes that of the creation and annihilation operators rather than imposing any extra physical assumption.

For invariant-normalized scalar mode extraction, take the Klein-Gordon inner product of $f_p$ with the field. The positive-frequency contribution has coefficient $E_p+E_q$ and spatial integral $(2\pi {)}^3{\delta }^3(\mathbf{p}-\mathbf{q})$. The negative-frequency contribution has coefficient $E_p-E_q$ and spatial integral $(2\pi {)}^3{\delta }^3(\mathbf{p}+\mathbf{q})$, so it vanishes because $E_{-p}=E_p$. ConsequentlyTaking the Hermitian adjoint, with the order of the scalar factors immaterial, yieldsEquivalently $a(\mathbf{p})=\int d^{3}x{f}_p^{\ast }(E_p\varphi +i\pi )$ and $a^{†}(\mathbf{q})=\int d^{3}y{f}_q(E_q\varphi -i\pi )$. At a common time their operator commutator therefore isThe same calculation gives $[a(\mathbf{p}),a(\mathbf{q})]=[a^{†}(\mathbf{p}),a^{†}(\mathbf{q})]=0$: the surviving factor is an energy difference supported at opposite spatial momenta. These are the bosonic canonical commutation relations in relativistic normalization of a one-particle state.

Choose the Fock vacuum by $a(\mathbf{p})|0⟩=0$ and $⟨0|0⟩=1$. Only the annihilator-creator product contributes to the Wightman function, givingUsing time ordering and the reverse product for $y^0>x^0$, the Feynman propagator, with the convention $D_F=i{\Delta }_F$ in this calculation, isIn particular the denominator in the spatial measure is $2E_p$ in both terms.

To verify the four-dimensional Fourier transform representation, let $\tau =x^0-y^0$ and integrate the energy variable first:The Feynman i-epsilon prescription puts the positive-energy pole at $E_p-i0$ and the negative-energy pole at $-E_p+i0$. For $\tau >0$, the contour integral closes in the lower half-plane with clockwise orientation. The residue theorem multiplies the residue $i{e}^{-i{E}_p\tau }/(2E_p)$ by $-i$, giving $e^{-i{E}_p\tau }/(2E_p)$. For $\tau <0$, it closes counterclockwise above: multiplying the residue $-i{e}^{i{E}_p\tau }/(2E_p)$ by $i$ gives $e^{i{E}_p\tau }/(2E_p)$. Thus $I(\tau )=e^{-i{E}_p|\tau |}/(2E_p)$. After inserting the spatial exponential, reversing $\mathbf{p}$ in the negative-time term gives exactly the time ordering expression above. HenceThis equality is understood as a distribution limit; the same prescription gives $(\square +m^2)D_F(x-y)=-i{\delta }^4(x-y)$.

All three fields have mass $m$. In the interaction picture the quantum fields evolve with the free Hamiltonian operator, so their equations areThe interactions evolve the states instead. For $\chi \in \{\varphi ,\psi ,\Phi \}$ the appropriate mode expansion of a free field isIndependent species have commuting creation and annihilation operators. The full set of canonical commutation relations isThese follow from the separate equal-time canonical commutation relations for the three real scalar fields. For comparison, in the Heisenberg picture the full Euler-Lagrange field equations contain interactions: $(\square +m^2){\varphi }_H=-g{\varphi }_H{\Phi }_H$, $(\square +m^2){\psi }_H=-g{\psi }_H{\Phi }_H$, and $(\square +m^2){\Phi }_H=-\frac{g}{2}({\varphi }_H^2+{\psi }_H^2)$. These are distinct from the free equations used in the interaction picture.

There are no derivative couplings, so the interaction Hamiltonian is $H_I(t)=-\int d^{3}x{\mathcal{L}}_I(x)$. The interaction picture evolution operator obeysIterating its integral equation gives the Dyson seriesThe ordered integration region is equivalent to the unrestricted region with time ordering and the factor $1/n!$. Taking the scattering limit $t_0\to -\infty$, $t\to \infty$, with the usual adiabatic prescription for perturbation theory, therefore yields the S-matrixAll fields inside this expression are interaction picture fields.

Use relativistic normalization of a one-particle state and take $|i⟩=a_{\varphi }^{†}(\mathbf{p})a_{\psi }^{†}(\mathbf{q})|0⟩$, $|f⟩=a_{\varphi }^{†}({\mathbf{p}}^{\prime })a_{\psi }^{†}({\mathbf{q}}^{\prime })|0⟩$. Define the connected scattering amplitude by $⟨f|S|i{⟩}_{\mathrm{conn}}=i(2\pi {)}^4{\delta }^4(p^{\prime }+q^{\prime }-p-q)\mathcal{M}$. The identity contribution describes no scattering; the term linear in $g$ cannot connect these four external particles. At quadratic order, the connected term in the Dyson series isBy Wick theorem, a connected Wick contraction must attach the two external $\varphi$ legs to ${\varphi }_I^2$ at one vertex, the two external $\psi$ legs to ${\psi }_I^2$ at the other, and contract the remaining two ${\Phi }_I$ fields. The two assignments of species to $x,y$ cancel the Dyson factor $1/2!$. At either vertex, the $2!$ assignments of its identical fields to the incoming and outgoing particle cancel the interaction factor $1/2$. Equivalently, the coefficient $-g^2/8$ is multiplied by $2\times 2\times 2$, giving $-g^2$. Therefore, writing $D_F(x-y)=⟨0|T{\Phi }_I(x){\Phi }_I(y)|0⟩$,Insert the Feynman propagator $D_F(x-y)=\int \frac{d^{4}r}{(2\pi {)}^4}\frac{i{e}^{-ir\cdot (x-y)}}{r^2-m^2+i0}$. The two vertex integrals impose $r=p^{\prime }-p$ and $p^{\prime }+q^{\prime }=p+q$. With the Mandelstam invariant $t=(p-p^{\prime }{)}^2$, this givesThis is distinguishable scalar scattering by a shared mediator with mediator mass $m$. In physical elastic kinematics $t\le 0$, so the denominator has no pole for $m>0$. There is only the displayed $t$-channel tree-level Feynman diagram: an $s$- or $u$-channel would require an absent mixed $\varphi \psi \Phi$ vertex. Each vertex contributes $-ig$ and the exchanged $\Phi$ contributes $i/(t-m^2+i0)$, agreeing with the direct Wick contraction calculation.

The interaction contains no time derivatives, so $\pi =\dot{\varphi }$. The Legendre transform in mechanics givesThusHere $H_0=\int {\mathcal{H}}_0$ is the free Hamiltonian operator of mass $m$, and $H_I=\int {\mathcal{H}}_I$ is the interaction Hamiltonian.

In the interaction picture, operators evolve with $H_0$ and the states with $H_I(t)=e^{i{H}_{0}t}{H}_I{e}^{-i{H}_{0}t}$. With $U_I(t_0,t_0)=I$, the state evolution satisfies $i{\partial }_t{U}_I(t,t_0)=H_I(t)U_I(t,t_0)$. Integrating once and iterating gives the Dyson seriesEquivalently it is the time ordering of the exponential. Taking the infinite-time scattering limit, with adiabatic switching understood, gives the scattering matrixThe field in the interaction is the free interaction-picture field, which is essential for applying the free-field contractions.

Use relativistic normalization of a one-particle state, $|\mathbf{p}⟩=\sqrt{2E_{\mathbf{p}}}{a}^{†}(\mathbf{p})|0⟩$, so each external scalar contraction contributes its plane-wave phase without an extra $1/\sqrt{2E}$ factor. For the connected on-shell two-to-two scattering amplitude, the first Dyson series term is $-i\lambda \int d^{4}x{\varphi }_I(x{)}^4/4!$. The Wick theorem gives $4!$ ways to attach the two incoming and two outgoing external particles to the four fields, canceling the denominator. ConsequentlywhereThe delta function expresses four-momentum conservation. The connected scattering convention removes spectator, vacuum and external self-energy contributions; equivalently at this order one can normal-order the interaction and keep the physical external mass fixed. These contributions should not be mistaken for additional connected four-point diagrams.