Andrews's carbon dioxide experiment Created 2026-10-14 Updated 2026-10-18
The 1869 The Bakerian Lecture: On the Continuity of the Gaseous and Liquid States of Matter by Thomas Andrews describes dried carbon dioxide trapped above mercury in a sealed capillary tube. A steel screw pressurized water in a strong copper tube; movable mercury transmitted the load. A second capillary tube held air as a pressure gauge. Flowing water around the visible capillary tubes controlled temperature; a thermometer read the bath. A cathetometer read column positions, converted to volume readings using weighed-mercury calibration.[ref]
Below the critical temperature, compression produced a visible liquid–gas boundary; above it, large density changes occurred without that boundary. Three trials gave as his critical temperature. Purity checks detected residual air; mercury height corrections accounted for unequal hydrostatic pressures. He explicitly left air nonideality and pressure-induced tube-capacity corrections unresolved, so his air-gauge pressures were approximate. These readouts support a liquid-gas critical point; they do not measure a homogeneous unstable loop or establish universal quantitative accuracy of the later Van der Waals equation.[ref]
Figure 1. . Original functional schematic, not a scale reconstruction. The water circuit transmits compression through mercury to two samples; separate temperature jackets permit control of the sample and air gauge. The right panels distinguish a visible liquid–gas liquid meniscus from a single thermodynamic phase. Interpret alongside the experimental limitations above. Details.
A disappearing liquid meniscus by itself has more than one possible explanation: in ordinary subcritical condensation or evaporation, one thermodynamic phase can simply run out. The stronger critical-point inference combines temperature control, compression readings and the existence of a continuous route around the endpoint of the phase coexistence curve. On that route a dilute gas can become dense without crossing a two-phase boundary. This is what continuity of liquid and gas means; it does not remove their distinct equilibrium number densities below .
In his 12 December 1910 Nobel lecture, Johannes Diderik van der Waals explained gases and liquids through the same moving molecules, with attraction and finite size modifying their pressure. He also rejected the idea that constant should give universal numerical agreement. His critical-volume discussion explicitly retained derivatives of a volume-dependent : the familiar follows only when those derivatives are neglected. Thus the elegant constant-parameter Van der Waals critical point is a model result whose limitations were already part of its author's account.[ref]