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A physicist whose research joined waves, optics, acoustics and precise measurement. He maintained a laboratory at Terling and served as Cavendish professor of experimental physics from 1879 to 1884. At Cambridge he developed laboratory courses; later he donated his Nobel award proceeds toward a Cavendish laboratory extension.^[ref]

The Rayleigh-Ramsay argon density experiment, pursued with William Ramsay, connects a small discrepancy in gas weighing to chemical separation. Its lesson is practical: agreement within one preparation method does not ensure that a second method produces the same chemical substance. The gas density model explains how composition and filling conditions both affect the readout.

In his 1895 lecture, Lord Rayleigh compared gas masses in a globe under matched pressure and temperature. Removing oxygen from air left gas about half a percent heavier than nitrogen prepared entirely from chemical sources. Several preparation routes reproduced the difference; hydrogen contamination was a concern. An eight-month storage test re-established the filling conditions: simply reweighing a sealed globe could not test a change in molar mass. William Ramsay concentrated the residual gas by circulating the mixture over hot magnesium, which consumed nitrogen. A spectral test checked remaining nitrogen. Agreement of spectra from this route and the alternative spark-and-alkali separation supported a common residual gas.^[ref]

The density difference alone identifies neither a unique chemical element nor its concentration. A heavier contaminant, a lighter reference contaminant, or unmatched filling conditions can all shift a weighing. A separation process and an optical spectrum provide additional observations. This combination makes the experiment powerful: the anomaly motivates another operation whose result can be checked independently.

A chemist who led the chemistry department at University College London from 1887 to 1913. His isolation of argon followed John William Strutt, 3rd Baron Rayleigh's observation that atmospheric nitrogen had greater density than chemically prepared nitrogen.^[ref]