Atoms exist and last for a long time, while in classical electromagnetic theory punctual orbiting electrons should emit radiation quickly and fall into the nucleus: physics.stackexchange.com/questions/20003/why-dont-electrons-crash-into-the-nuclei-they-orbit
In other sections:
- black-body radiation experiment
- Einstein solid experiments, which are analogous to black body radiation experiments
- emission spectrum
- electron diffraction experiments such as:
Bibliography:
- web.mit.edu/course/5/5.73/oldwww/Fall04/notes/Experimental_Evidence_for_Quantum_Mechanics.pdf Experimental Evidence for Quantum Mechanics
The discovery of the photon was one of the major initiators of quantum mechanics.
Light was very well known to be a wave through diffraction experiments. So how could it also be a particle???
This was a key development for people to eventually notice that the electron is also a wave.
This process "started" in 1900 with Planck's law which was based on discrete energy packets being exchanged as exposed at On the Theory of the Energy Distribution Law of the Normal Spectrum by Max Planck (1900).
This ideas was reinforced by Einstein's explanation of the photoelectric effect in 1905 in terms of photon.
In the next big development was the Bohr model in 1913, which supposed non-classical physics new quantization rules for the electron which explained the hydrogen emission spectrum. The quantization rule used made use of the Planck constant, and so served an initial link between the emerging quantized nature of light, and that of the electron.
The final phase started in 1923, when Louis de Broglie proposed that in analogy to photons, electrons might also be waves, a statement made more precise through the de Broglie relations.
This event opened the floodgates, and soon matrix mechanics was published in quantum mechanical re-interpretation of kinematic and mechanical relations by Heisenberg (1925), as the first coherent formulation of quantum mechanics.
It was followed by the Schrödinger equation in 1926, which proposed an equivalent partial differential equation formulation to matrix mechanics, a mathematical formulation that was more familiar to physicists than the matrix ideas of Heisenberg.
Inward Bound by Abraham Pais (1988) summarizes his views of the main developments of the subjectit:
- Planck's on the discovery of the quantum theory (1900);
- Einstein's on the light-quantum (1905);
- Bohr's on the hydrogen atom (1913);
- Bose's on what came to be called quantum statistics (1924);
- Heisenberg's on what came to be known as matrix mechanics (1925);
- and Schroedinger's on wave mechanics (1926).
Bibliography:
- physics.stackexchange.com/questions/18632/good-book-on-the-history-of-quantum-mechanics on Physics Stack Exchange
- www.youtube.com/watch?v=5hVmeOCJjOU A Brief History of Quantum Mechanics by Sean Carroll (2020) Given at the Royal Institution.
These are the key mathematical ideas to understand!!
There are actually a few formulations out there. By far the dominant one as of 2020 has been the Schrödinger picture, which contrasts notably with the Heisenberg picture.
Another well known one is the de Broglie-Bohm theory, which is deterministic, but non-local.
The first quantum mechanics theories developed.
Their most popular formulation has been the Schrödinger equation.
This only makes sense if the photon exists, there is no classical analogue, because the energy of classical waves depends only on their amplitude, not frequency.
Experiments that suggest this:
The first really good quantum mechanics theory made compatible with special relativity was the Dirac equation.
And then came quantum electrodynamics to improve it: Dirac equation vs quantum electrodynamics.
TODO: does it use full blown QED, or just something intermediate?
www.youtube.com/watch?v=NtnsHtYYKf0 "Mercury and Relativity - Periodic Table of Videos" by Periodic Videos (2013). Doesn't give the key juicy details/intuition. Also mentioned on Wikipedia: en.wikipedia.org/wiki/Relativistic_quantum_chemistry#Mercury
Quantum field theory lecture by Tobias Osborne (2017) mentions that quantization is a guess.
Quantum superposition is really weird because it is fundamentally different than "either definite state but I don't know which", because the superposition state leads to different measurements than the non-superposition state.
Examples:
- www.youtube.com/watch?v=tt8gVXDsh7Q "Interference in quantum mechanics" by Looking Glass Universe (2015) shows how a left-right spin measurement has a defined value for a superposed half up half down state, but not for a pure up state.TODO can this be conducted? As mentioned in the video, this is closely linked to the fact that you can describe the wave function in multiple different bases (up/down or left/right), which is also at the root of the uncertainty principle.
- Video "Quantum Mechanics 9b - Photon Spin and Schrodinger's Cat II by ViaScience (2013)" gives a similar photon version
- it seems that the single particle double slit experiment can also be thought of as in terms of a superposition of "the particle goes through the right" and "the particle goes through the right", although it is a bit harder to thing about as it is not a discrete process
Quantum entanglement is often called spooky/surprising/unintuitive, but they key question is to understand why.
To understand that, you have to understand why it is fundamentally impossible for the entangled particle pair be in a predefined state according to experiments done e.g. where one is deterministically yes and the other deterministically down.
In other words, why local hidden-variable theory is not valid.
How to generate entangled particles:
- particle decay, notably pair production
- for photons, notably: spontaneous parametric down-conversion, e.g.: www.youtube.com/watch?v=tn1sEaw1K2k "Shanni Prutchi Construction of an Entangled Photon Source" by HACKADAY (2015). Estimatd price: 5000 USD.