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Experimental verification of the Maxwell-Boltzmann distribution by
Ciro Santilli 40 Updated 2025-07-16
Most applications of the Maxwell-Boltzmann distribution confirm the theory, but don't give a very direct proof of its curve.
Here we will try to gather some that do.
S page 146.
For this sub-case, we can define the Lie algebra of a Lie group as the set of all matrices such that for all :If we fix a given and vary , we obtain a subgroup of . This type of subgroup is known as a one parameter subgroup.
The immediate question is then if every element of can be reached in a unique way (i.e. is the exponential map a bijection). By looking at the matrix logarithm however we conclude that this is not the case for real matrices, but it is for complex matrices.
TODO example it can be seen that the Lie algebra is not closed matrix multiplication, even though the corresponding group is by definition. But it is closed under the Lie bracket operation.
The set of all invertible matrices forms a group: the general linear group with matrix multiplication. Non-invertible matrices don't form a group due to the lack of inverse.
Magic: The Gathering meta-based deck choice is a bimatrix game by
Ciro Santilli 40 Updated 2025-07-16
Ciro had initially Googled for the "4-card limit thought experiment" but he reached: www.channelfireball.com/articles/what-if-the-4-card-limit-was-abolished-in-modern/ "What if the 4-Card Limit Was Abolished in Modern?" by Frank Karsten (2018) and was much more pleased with the mathematical result. Like-minded people.
That links to www.channelfireball.com/articles/what-if-the-4-card-limit-was-abolished-in-modern/ the related article: "The Mythic Invitational's Duo Standard Format Game Theory Optimized" by Frank Karsten (2019) which explains well how Nash equilibrium is naturally reached: if there is any imbalance, someone can take advantage of it, and then it rebalances. Therefore once you've calculated the equilibrium, your best course of action is to pick a deck at random from a list of possible winners.
To better understand the discussion below, the best thing to do is to read it in parallel with the simplest possible example: Schrödinger picture example: quantum harmonic oscillator.
"Making a measurement" for an observable means applying a self-adjoint operator to the state, and after a measurement is done:Those last two rules are also known as the Born rule.
- the state collapses to an eigenvector of the self adjoint operator
- the result of the measurement is the eigenvalue of the self adjoint operator
- the probability of a given result happening when the spectrum is discrete is proportional to the modulus of the projection on that eigenvector.For continuous spectra such as that of the position operator in most systems, e.g. Schrödinger equation for a free one dimensional particle, the projection on each individual eigenvalue is zero, i.e. the probability of one absolutely exact position is zero. To get a non-zero result, measurement has to be done on a continuous range of eigenvectors (e.g. for position: "is the particle present between x=0 and x=1?"), and you have to integrate the probability over the projection on a continuous range of eigenvalues.In such continuous cases, the probability collapses to an uniform distribution on the range after measurement.The continuous position operator case is well illustrated at: Video "Visualization of Quantum Physics (Quantum Mechanics) by udiprod (2017)"
Self adjoint operators are chosen because they have the following key properties:
- their eigenvalues form an orthonormal basis
- they are diagonalizable
Perhaps the easiest case to understand this for is that of spin, which has only a finite number of eigenvalues. Although it is a shame that fully understanding that requires a relativistic quantum theory such as the Dirac equation.
The next steps are to look at simple 1D bound states such as particle in a box and quantum harmonic oscillator.
This naturally generalizes to Schrödinger equation solution for the hydrogen atom.
The solution to the Schrödinger equation for a free one dimensional particle is a bit harder since the possible energies do not make up a countable set.
This formulation was apparently called more precisely Dirac-von Neumann axioms, but it because so dominant we just call it "the" formulation.
Quantum Field Theory lecture notes by David Tong (2007) mentions that:
if you were to write the wavefunction in quantum field theory, it would be a functional, that is a function of every possible configuration of the field .
Notation used in quantum mechanics.
Ket is just a vector. Though generally in the context of quantum mechanics, this is an infinite dimensional vector in a Hilbert space like .
Bra is just the dual vector corresponding to a ket, or in other words projection linear operator, i.e. a linear function which can act on a given vector and returns a single complex number. Also known as... dot product.
For example:is basically a fancy way of saying:that is: we are taking the projection of along the direction. Note that in the ordinary dot product notation however, we don't differentiate as clearly what is a vector and what is an operator, while the bra-ket notation makes it clear.
The projection operator is completely specified by the vector that we are projecting it on. This is why the bracket notation makes sense.
It also has the merit of clearly differentiating vectors from operators. E.g. it is not very clear in that is an operator and is a vector, except due to the relative position to the dot. This is especially bad when we start manipulating operators by themselves without vectors.
This notation is widely used in quantum mechanics because calculating the probability of getting a certain outcome for an experiment is calculated by taking the projection of a state on one an eigenvalue basis vector as explained at: Section "Mathematical formulation of quantum mechanics".
Making the projection operator "look like a thing" (the bra) is nice because we can add and multiply them much like we can for vectors (they also form a vector space), e.g.:just means taking the projection along the direction.
Ciro Santilli thinks that this notation is a bit over-engineered. Notably the bra's are just vectors, which we should just write as usual with ... the bra thing makes it look scarier than it needs to be. And then we should just find a different notation for the projection part.
Maybe Dirac chose it because of the appeal of the women's piece of clothing: bra, in an irresistible call from British humour.
But in any case, alas, we are now stuck with it.
This is basically what became the dominant formulation as of 2020 (and much earlier), and so we just call it the "mathematical formulation of quantum mechanics".
An "alternative" formulation of quantum mechanics that does not involve operators.
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