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For a normalized trial state $|\psi ⟩={\sum }_n{c}_n|n⟩$ in the form domain of a bounded-below Hamiltonian, the quantum variational principle gives $⟨H⟩={\sum }_n|c_n{|}^2{E}_n\ge E_0$. Thus each trial expectation is an upper bound for the ground-state energy. The same spectral argument covers a continuum: for a decaying potential whose essential spectrum begins at $0$, a negative trial expectation guarantees a negative-energy bound state.

For the stated exponential trial function, normalization follows from $4{\alpha }^3{\int }_0^{\infty }{r}^2{e}^{-2\alpha r}dr=1$. The kinetic expectation, using $\int |\nabla \psi {|}^2$, is ${\hslash }^2{\alpha }^2/(2m)$. The potential expectation is $-4A{\alpha }^3{\int }_0^{\infty }r{e}^{-(\mu +2\alpha )r}dr$. ThereforeThe exponential variational bound for the Yukawa potential at $\alpha =\mu /2$ gives $E=(\mu /8)({\hslash }^2\mu /m-A)<0$ if $\mu <Am/{\hslash }^2$. Thus a bound state necessarily exists in the stated range.

For $\mu \ge Am/{\hslash }^2$, this single-exponential family cannot prove binding: the maximum of $4A\alpha /(\mu +2\alpha {)}^2$ is $A/(2\mu )$, so every $E(\alpha )\ge 0$. This does not prove absence of bound states.

The equality case can in fact be strengthened. At $\mu =Am/{\hslash }^2$, use normalized exponentials ${\psi }_{\mu /2},{\psi }_{\mu }$ and write $Q={\hslash }^2{\mu }^2/m$. Their matrix elements areThe Rayleigh numerator for ${\psi }_{\mu /2}+ϵ{\psi }_{\mu }$ is negative for sufficiently small $ϵ>0$, and its norm is nonzero. Hence binding also holds at equality, and by continuity in a small interval beyond it. For arbitrary larger $\mu$, these trials alone do not settle existence; a nonnegative variational upper bound cannot establish a nonnegative ground-state energy.

Taking $\mathbf{n}$ along a coordinate axis gives ${\sigma }_i^2=I$. Taking $\mathbf{n}=(e_i+e_j)/\sqrt{2}$ for $i\ne j$ gives $\{{\sigma }_i,{\sigma }_j\}=0$. Combining this anticommutator relation with the specified commutator givesand contraction with $a_i{b}_j$ provesThe operators for spin angular momentum, $S_i=\hslash {\sigma }_i/2$, satisfy $[S_i,S_j]=i\hslash {ϵ}_{ijk}{S}_k$ and $S^2=3{\hslash }^{2}I/4$, identifying spin $1/2$. The usual irreducible spin space is two-dimensional; the assumptions also allow repeated copies of it if no Hilbert-space dimension is specified.

Since $\mathbf{n}\cdot \mathbf{\sigma }$ is Hermitian and squares to $I$, $P_{\pm }=(I\pm \mathbf{n}\cdot \mathbf{\sigma })/2$ are Hermitian, $P_{\pm }^2=P_{\pm }$, $P_{+}{P}_{-}=0$ and $P_{+}+P_{-}=I$. They are its spectral projectors. WriteEach nonzero term is a scalar multiple of a normalized eigenstate with eigenvalue $\pm 1$. The Born rule gives, for normalized $|\chi ⟩$,If $(\mathbf{m}\cdot \mathbf{\sigma })|\chi ⟩=|\chi ⟩$, expectation of $\{\mathbf{m}\cdot \mathbf{\sigma },\mathbf{a}\cdot \mathbf{\sigma }\}=2\mathbf{m}\cdot \mathbf{a}$ gives $⟨\mathbf{a}\cdot \mathbf{\sigma }⟩=\mathbf{m}\cdot \mathbf{a}$. Taking $\mathbf{a}=\mathbf{n}$ yields $\boxed{\mathbb{P}(\text{up along }\mathbf{n})=\frac{1}{2}(1+\mathbf{n}\cdot \mathbf{m})}$.

Compatibility of the auxiliary system, computed on a fundamental matrix of solutions, gives the zero-curvature conditionIndeed equality of the mixed derivatives gives $(U_t+UV-V_x-VU)\Psi =0$. A single possibly zero vector solution would not justify the matrix identity; compatibility means a full fundamental family.

Put $H=W_t-VW$. Using the zero-curvature condition gives $H_x=UH$. At $x=0$, $W_t=0$ and hence $H(0)=-V(0)$. Uniqueness of the initial-value problem gives $H=-WV(0)$, or $W_t=VW-WV(0)$. Periodicity implies $V(2\pi )=V(0)=v$, so the monodromy matrix $w=W(2\pi )$ obeys the Lax equationCyclicity of the trace yields $\frac{d}{dt}\mathrm{tr}(w^k)=k\mathrm{tr}(w^{k-1}[v,w])=0$ for every $k\ge 1$.

There is a genuine factor-of-two error in the printed sine-Gordon pair. Assign the second printed matrix to $U$ and the first to $V_{\mathrm{print}}$:Direct multiplication givesThus the printed matrices encode $u_{xt}=2\sin u$.

For the stated Sine-Gordon equation, explicitly repair the first prefactor by taking $V=V_{\mathrm{print}}/2$, that is $1/(4i\lambda )$. Its zero-curvature condition becomes $u_{xt}=\sin u$. For this corrected pair, $\mathrm{tr}(w(t,\lambda {)}^k)$ is conserved for every $\lambda \ne 0$. Since $U$ is entire in $\lambda$, so are $W$ and these traces. Their Taylor coefficients in $\lambda$ supply an infinite family of first integrals, by the identity theorem extending conservation through $\lambda =0$. At a fixed spectral parameter the higher traces of a $2\times 2$ matrix are related by the Cayley-Hamilton theorem; no independence of the resulting first integrals is claimed.