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Time-independent perturbation theory expands the eigenvalues and eigenstates of $H_0+V$ in powers of a small perturbation $V$.

This is the stationary branch of perturbation theory.

Expanding a state in unperturbed energy eigenstates with their free phases converts the time-dependent Schrodinger equation into coupled equations for slowly varying amplitudes. To first order, the perturbation on the right-hand side acts on the initial unperturbed state.

This is the time-dependent branch of perturbation theory; its corrections describe transition amplitudes.

Independent quantum systems combine by tensor product, with local operators acting as $A\otimes I$ or $I\otimes B$.

A Fermi oscillator has nilpotent lowering operator $B$, anticommutator $B{B}^{†}+B^{†}B=1$, and occupation Hamiltonian $B^{†}B$ with levels zero and one.

For unit mass and angular frequency,The level with total occupation $N=n_x+n_y$ has energy $N+1$ and degeneracy $N+1$ in units where $\hslash =1$.

Its energies are $E_N=\hslash \omega (N+3/2)$, and level $N$ has degeneracy $\left(\genfrac{}{}{0ex}{}{N+2}{2}\right)$.

The quantum harmonic oscillator describes a particle of mass $m>0$ in a quadratic potential energy with angular frequency $\omega >0$. In the position representation its Quantum Hamiltonian isThe model is useful far beyond a literal spring: a Taylor series about a stable equilibrium with positive potential curvature has this quadratic term as its leading nonconstant approximation. The pure quartic oscillator has zero curvature at its minimum, so that particular approximation does not apply. ^[ref].

In units with $\hslash =1$, creation and annihilation operators giveHere $N$ is the number operator. Restoring the reduced Planck constant, the energy eigenvalues are $E_n=\hslash \omega (n+1/2)$ for $n=0,1,2,\dots$: neighboring levels are separated by $\hslash \omega$, and the ground-state energy is the zero-point energy $\hslash \omega /2$.

With length scale $\ell =\sqrt{\hslash /(m\omega )}$ and dimensionless coordinate $u=x/\ell$, the ground state is the normalized Gaussian wave packetFor $\hslash =m=\omega =1$, this is precisely the $a=1$ trial wavefunction in the quantum variational principle. The balance of kinetic energy and potential energy therefore recovers the exact ground-state energy using only Gaussian integrals.

Orbital angular momentum is $L=-i\hslash ,x\times \nabla$; in particular $L_3=-i\hslash (x_1{\partial }_{x_2}-x_2{\partial }_{x_1})$.

The infinite square well is an ideal confinement model with potential energy $V(x)=0$ for $0<x<L$ and infinite walls outside. The walls impose Dirichlet boundary conditions $\varphi (0)=\varphi (L)=0$ and a vanishing exterior wavefunction. Inside, the time-independent Schrödinger equation isThe first wall removes the cosine term; the second requires $\sin (kL)=0$, hence $k=n\pi /L$. The $n=0$ solution is identically zero and cannot satisfy wavefunction normalization. Each energy eigenstate has $n-1$ interior nodes of a standing wave, at $x=jL/n$ for $j=1,\dots ,n-1$. More curvature costs more kinetic energy, explaining the $n^2$ growth. The positive ground-state energy is a confinement effect: a constant zero-energy wavefunction cannot satisfy both walls and remain normalized.

For an Electron with mass $m_e=9.1093837139\times 10^{-31}\mathrm{kg}$ in a box of length $L=1\mathrm{nm}$, use $h=6.62607015\times 10^{-34}\mathrm{J}\mathrm{s}$ and $1\mathrm{eV}=1.602176634\times 10^{-19}\mathrm{J}$. These constants are from the 2022 CODATA adjustment. ^[ref]. Substitution givesDoubling $L$ quarters every energy eigenvalue; doubling $m$ halves them. This scaling makes the particle in a box useful for estimating confinement energies before attempting a more realistic calculation. A finite square well permits exterior tails for bound states and has only finitely many bound energy eigenstates. For an Electron, the scalar box calculation assumes fixed spin and no spin-dependent interactions.

For the ground state, the probability of finding the particle in the middle half of the box is fully computable:Thus half the available length contains about $81.8\%$ of the probability. The figure contrasts the signed wavefunctions with their nonnegative probability densities: a negative lobe is an amplitude with opposite quantum phase, not negative probability.

An equal quantum superposition of the first two energy eigenstates gives a simple example of moving density:Its density period is $T=h/(E_2-E_1)\approx 3.66608\mathrm{fs}$ for the Electron box above. At $t=0$ the cross term enhances the left side; at $T/4$ it vanishes; at $T/2$ it enhances the right side. More quantitatively,which takes the values $0.924413$, $0.5$, and $0.075587$ at those times. Orthogonality keeps the total probability one throughout. An energy measurement still returns $E_1$ or $E_2$ with equal probabilities: changing position density arises from relative quantum phase, not changing populations. A mixed state describing a statistical mixture with those populations has the constant probability density $({\varphi }_1^2+{\varphi }_2^2)/2$; it lacks this matter-wave interference term.

Ehrenfest’s theorem makes expectation values obey Hamiltonian commutator equations analogous to classical motion.

For a possibly time-dependent observable $O$,

In position representation, momentum is minus i hbar times spatial differentiation.

In position representation, the position operator multiplies a wavefunction by its coordinate.

A reflectionless potential transmits every scattering state with zero reflected probability.

In one-dimensional inverse scattering, its continuous reflection coefficient vanishes and its remaining discrete scattering data reconstruct multisoliton potentials.

Supersymmetric quantum mechanics factors partner Hamiltonians through first-order operators. Its odd supercharges anticommute to the Hamiltonian; on a Riemannian manifold, the Hilbert space can be realized by square-integrable differential forms with supercharges given by a differential and its adjoint.

Quantum scattering compares a wavefunction's incoming and outgoing asymptotic components.

A delta potential is a point interaction imposing continuity of the wavefunction and a jump in its derivative.

A finite square well is a bounded interval on which the potential is lower than outside, supporting matched oscillatory and exponential states.

For a normalized wavefunction $\psi (x)=A{e}^{-B{x}^2}$ with $\mathrm{Re}B>0$,

For normalized independent states with $H|\psi ⟩=g|\varphi ⟩$ and $H|\varphi ⟩=g^{\ast }|\psi ⟩$, Hermiticity is equivalent to $g⟨\psi |\varphi ⟩\in \mathbb{R}$. Writing $r=g⟨\psi |\varphi ⟩/|g|$, the orthonormal eigenstates are proportional towith eigenvalues $\pm |g|$ and squared norms $2(1\pm r)$.