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An adiabat is a curve representing a quasistatic adiabatic change. In a reversible description it is also a curve of constant entropy. For an ideal gas with constant heat-capacity ratio $\gamma$, it obeys $p{V}^{\gamma }=\mathrm{constant}$. A general irreversible adiabatic process need not follow this equilibrium-state curve and can produce entropy.

A heat engine's thermal efficiency is net work out divided by heat absorbed,where both heat quantities are positive magnitudes. The last equality follows from the first law over a complete cycle.

Use $n$ moles of an ideal gas with constant molar $C_V,C_p$ and $\gamma =C_p/C_V>1$. For the Otto cycle, reversible adiabats give $T_2=T_1{r}^{\gamma -1}$ and $T_3/T_4=r^{\gamma -1}$. Isochoric heat input and rejection are $Q_{\mathrm{in}}=n{C}_V(T_3-T_2)$ and $Q_{\mathrm{out}}=n{C}_V(T_4-T_1)$. ThereforeThe denominator's temperature difference is $r^{\gamma -1}$ times the numerator's difference.

For the ideal Atkinson cycle, heating at fixed volume gives $T_3/T_2=r_p$. The longer expansion ends when $p_{4^{\prime }}=p_1$. Combining the adiabatic pressure–temperature relation with $p_2/p_1=r^{\gamma }$ yieldsAlso $V_{4^{\prime }}=V_1{r}_p^{1/\gamma }>V_1$ for $r_p>1$. The PDF asks explicitly for $T_3,T_{4^{\prime }}$; the transcription additionally names $T_2$, which is supplied above too.

Heat input remains $n{C}_V{T}_1{r}^{\gamma -1}(r_p-1)$, while the isobaric return rejects $n{C}_p{T}_1(r_p^{1/\gamma }-1)$. Hence the Atkinson efficiency advantage from extended expansion is quantified byCompare cycles with the same initial state, compression ratio and heat input. The extra expansion and constant-pressure return enclose positive extra work,It uses heat that the Otto cycle would reject, while $Q_{\mathrm{in}}$ is unchanged. Equivalently, concavity gives $\gamma (r_p^{1/\gamma }-1)<r_p-1$, so ${\eta }_A>{\eta }_O$ for $r_p>1$ under this matched comparison. This is an ideal-cycle result; the question's named real-engine application is not needed to establish it.

Label the initial state 1, the end of compression 2, the end of constant-pressure heating 3, and the end of adiabatic expansion 4. The volume sequence is $V_1\to V_2\to V_3\to V_1\to V_1$, with $V_2<V_3<V_1$. The Diesel cycle has a compression adiabat $1\to 2$, a horizontal constant-pressure heat-input segment $2\to 3$, an expansion adiabat $3\to 4$, and a vertical constant-volume cooling segment $4\to 1$.

For an ideal gas, a reversible adiabat obeys $p{V}^{\gamma }=\mathrm{constant}$, so it falls more steeply than an isotherm. The expansion adiabat lies above the compression adiabat at equal volume between $V_3$ and $V_1$, giving a clockwise cycle with positive work output.

For $\rho \to 1^{+}$, Taylor expansion gives ${\rho }^{\gamma }-1=\gamma (\rho -1)+O((\rho -1{)}^2)$. The vanishing-cutoff limit of the Diesel cycle isThe maximum temperature tends to $T_2=T_1{r}^{\gamma -1}$, while the minimum stays at $T_1$. A Carnot engine between those limiting extrema hasso the limiting efficiencies coincide. At exactly $V_3=V_2$, however, both heat input and net work vanish, and the cycle retraces its compression adiabat. The efficiency there is an undefined $0/0$; the boxed value is the continuous limit for neighbouring nonzero cycles, not finite work at zero heat input.

For a finite cutoff ratio $\rho >1$, the Carnot comparison uses $T_{\max }=T_3=T_1{r}^{\gamma -1}\rho$, giving ${\eta }_C=1-1/(r^{\gamma -1}\rho )$. The Diesel cycle has smaller efficiency. For example,which makes its rejected/input heat ratio larger than the Carnot ratio.

For a reversible adiabatic change, $dS=0$, equivalently $C_{V}dT=-pdV$. Substitute $p=RT/(V-b)$:Integration, with fixed positive reference values $T_{\ast },W_{\ast }$, givesSince $T=p(V-b)/R$ and $\gamma =1+R/C_V$,The relation applies to the quasistatic reversible adiabat. Adiabatic heat isolation alone does not enforce it for an irreversible process which generates entropy. The shifted volume $V-b$, rather than $V$ itself, is the appropriate coordinate in this model.

Take the convection to maintain a dry, nearly reversible adiabat, with specific gas constant $R$. Hydrostatic equilibrium and an ideal-gas equation of state will be used separately to convert pressure to height. For an adiabatic displacement, the first law of thermodynamics in enthalpy form givesThe adiabat with linear heat capacity follows by integrating from the surface: this gives the monotone implicit temperature–pressure relationAn explicit form, using the positive real Lambert W branch, isAs $B\to 0$, $T=T_s(p/p_s{)}^{R/A}$. At fixed $p<p_s$,Larger heat capacity therefore keeps the upper atmosphere warmer at the same pressure. Equivalently $d\ln T/d\ln p=R/(A+BT)$ becomes smaller. The original normalized sketch below shows the resulting family of profiles; no particular gas constants or surface temperature are assumed there.

The height equations areIntegrating the latter givesThe physically selected root starts at $T_s$ and decreases. Its formal upper boundary isAt that height $T\to 0$ and $p=p_s(T/T_s{)}^{A/R}{e}^{B(T-T_s)/R}\to 0$. The $B=0$ limit is $z_{\ast }=A{T}_s/g$. This finite-height zero is a property of the assumed polytropic-like model, not a claim that a real atmosphere reaches absolute zero: molecular heat capacities, composition, transport and the continuum ideal-gas description cease to support that extrapolation.

Let $D\ll 1$ be the remaining absorber optical depth, and retain the mixture's convective exponent ${\kappa }_a=R_a/c_{pa}$. The outgoing surface contribution is $\sigma T_s^4{e}^{-D}\simeq \sigma T_s^4(1-D)$. To first order, atmospheric emission is the column-mean source times $D$. If $4{\kappa }_a\simeq 1$, the adiabat gives $T(p{)}^4\simeq T_s^{4}p/p_a$, a source linear in mass/optical depth. Therefore its mean is $T_s^4/2$, or equivalently it is evaluated at $p_a/2$:Setting this equal to $L_{⊛}/4$ givesThe zero-opacity limit correctly gives $T_e$, while a small positive opacity raises the surface temperature slightly. The expression is a first-order thin-column result, not a formula to extend to its apparent pole at ${\tau }_{\infty }=2$. More generally, direct thin-column averaging gives $F_{\mathrm{atm}}\simeq D\sigma T_s^4/(1+4{\kappa }_a)$; the half-column value is exact at this order when $4{\kappa }_a=1$. The assumed convective thermal structure remains a modelling condition even when the gas becomes radiatively thin.

Assume an ideal gas dominated by carbon dioxide, constant mean molar heat capacity $C_p$, and a dry convective adiabat connecting the stated emitting layer to the ground. Conservation of entropy gives $C_{p}d\ln T=Rd\ln p$, where $R$ is the universal molar gas constant. ThusThe estimate extrapolates across a pressure ratio of $450$. It neglects radiatively stable layers, variable heat capacity, departures from an ideal gas and changes in composition; these approximations limit its accuracy. A brightness temperature observed from space cannot generally be equated to a unique material level, but this calculation uses the layer interpretation explicitly supplied by the question.