In an irreducible spin representation, the angular momentum lowering operator has squared norm factor . Multiplying these factors from the highest-weight vector gives the factorial normalization displayed above. All factorial arguments are integers even when is half-integral. This produces a consistent positive-coefficient phase convention for all weight states and fixes signs in subsequent isospin rotations.
Use the uncoupled angular momentum eigenstates and , with . For the Hamiltonian operator actually written in the paper, these are the energy eigenstates, with
The initial states are not all energy eigenstates of this operator. To find their energy populations, first perform the Clebsch-Gordan decomposition. The extremal states are and . Applying the total angular momentum lowering operator to the first gives
Similarly,
The initial preparation is an equal incoherent mixture of the four coupled states. Each extremal state contributes population to its one energy eigenvalue, while each nonextremal state contributes and of its own population to the two displayed components. The resulting Zeeman splitting is therefore
for nonzero . The relative populations are in this order; the two zero-energy states each have population . These Zeeman populations from an unpolarized angular-momentum multiplet remain constant under subsequent evolution by the stated static Hamiltonian operator, although off-diagonal quantum coherence can evolve.
There is a distinct weak-field model in which a retained spin-orbit interaction keeps isolated and one projects the magnetic perturbation into that quartet. The Landé g-factor is then , giving four shifts with equal populations. That calculation requires the additional projection or dominant spin-orbit interaction; it is not diagonalization of the full magnetic Hamiltonian operator specified here, which also mixes the sector.
With , angular momentum eigenstates have and . Their and eigenvalues are and . Adding spins and gives and, if , . For the Clebsch-Gordan coefficients to be nonzero one requires .
For , write for . The highest state and one application of the angular momentum lowering operator give
The lowering coefficient of the highest state is , while the two product-state coefficients before division are and . The last line is its normalized orthogonal complement. Its coefficient with maximal is positive, fixing the requested phase convention. All other coefficients for the allowed vanish.
For the decay, the final total intrinsic spin is . Combining it with integer orbital angular momentum to obtain permits only . Parity conservation gives . Thus .
For and initial , the last displayed coupled state shows that the spin-up probability, after ignoring the orthogonal orbital states, is . For , is the maximal coupled angular momentum and its highest state is . Therefore .
Operators, quantization and rotations. Angular momentum is the generator of spatial rotations. In quantum mechanics, its components are Hermitian operators on their appropriate domains and obey
These angular momentum commutation relations prevent all three components from having simultaneous sharp values. For example, the Robertson uncertainty principle gives . One conventionally diagonalizes and a selected component :
The allowed labels are and . An angular-momentum multiplet has states. The magnitude differs from the largest possible component ; the remaining components fluctuate even in a state with maximal .
The angular momentum lowering operator and its raising counterpart, , satisfy
The ladder terminates at . A rotation through angle about unit vector acts through the unitary operator . Thus quantized components and the continuous rotation of a state are compatible.
Orbital angular momentum. The orbital contribution is associated with motion in space:
For a spinless spatial wavefunction, the simultaneous angular eigenfunctions are the spherical harmonics , with and . Single-valued ordinary scalar spatial wavefunctions give integer orbital labels. In a central potential energy, , so stationary states may be labelled by these angular quantum numbers. The angular kinetic contribution appears in the radial equation as , the centrifugal potential. Noncentral interactions need not conserve these orbital labels.
Intrinsic spin and addition. Spin angular momentum is an intrinsic internal degree of freedom with the same commutation algebra. It is not the angular momentum of a small classical charged sphere literally rotating about its centre. For an electron, and , so in terms of the Pauli matrices. Its squared spin is . Other particles can have integer or half-integer spin, including spin zero.
For one particle with orbital and spin degrees of freedom, ; the two component sets commute with each other. Addition of angular momentum permits . The coupled states are linear combinations of the uncoupled with , determined by Clebsch-Gordan coefficients. A rotationally invariant spin-orbit interaction can conserve while mixing the separate component labels.
Angular momentum also carries a magnetic moment. For an electron's orbital motion and intrinsic spin,
The minus signs reflect negative electric charge. With the Bohr magneton , a spin projection has . A magnetic field can therefore distinguish angular-momentum states through their interaction energy .
Stern–Gerlach measurement. In the Stern-Gerlach experiment, atoms emerge from a heated source, pass through collimating apertures, traverse a strongly inhomogeneous magnetic field, and strike a position-sensitive screen. The beam is neutral, so its separation is interpreted through the atomic magnetic moment rather than the ordinary charged-particle Lorentz force. Near a chosen quantization direction, the interaction gives
A uniform field can exert a torque but would not separate the beam by this translational force; the gradient is essential. Different allowed magnetic-moment components become correlated with different trajectories. A classical ensemble with continuously varying orientations would yield a continuous spread, whereas discrete quantum components yield separated channels.
In the modern electronic description of ground-state silver, filled shells cancel their electronic angular momenta and the unpaired electron has , , . The effective electronic measurement therefore has two components, approximately , rather than an orbital , which is not allowed. For positive field gradient the electronic component has negative and deflects downward in this coordinate convention. Nuclear spin and hyperfine structure are neglected in this simplified two-channel account. Historically the original splitting preceded the electron-spin interpretation, so the modern explanation should not be confused with the original investigators' interpretation.
Figure 1.
A neutral atomic beam separates into two electronic magnetic-moment channels in a field gradient
. Details.
More generally a prepared spin state gives the two outcomes with probabilities . Selecting one channel prepares a state for further measurements. An ideal second analyser along the same axis then gives a definite result, whereas one along a perpendicular axis gives two equally likely outcomes for a spin-one-half eigenstate. This connects the apparatus directly to incompatible spin components and the Born rule. Angular momentum is quantized through its operator algebra; the Stern–Gerlach gradient turns that discrete internal information into spatially distinguishable outcomes.
The angular momentum eigenstates have eigenvalue , where the angular momentum quantum number is . For each , the magnetic quantum number runs in unit steps from to . Here that magnetic quantum number is , so only half-integer are compatible:
Integer cannot contain a eigenvalue . Applying the angular momentum lowering operator and using gives
The lowered vector is nonzero, since the adjoint operator identity gives
Finally, is a self-adjoint operator, so its eigenstates for distinct eigenvalues are orthogonal. Explicitly,
and hence .