Past exam of the chemistry A course of the University of Cambridge 2021 Paper 1 A3 b iii Solution 2026-10-20
The calculated rotational constant gives . At room temperature, taken as , the continuous maximum is ; comparing the adjacent integer populations gives . Taking instead gives and the same integer answer.
Rotational energy 2026-10-20
For a linear rigid rotor with moment of inertia , the energy eigenvalue at angular momentum quantum number is . Each level has statistical weight before additional symmetry or nuclear-spin restrictions.