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Set ${\omega }_1={\omega }_2=\omega$. Inverting the creation and annihilation operators givesSubstitute these expressions in $L_3=X_1{P}_2-X_2{P}_1$. Terms with two creation operators or two annihilation operators cancel because different modes commute. The remaining orbital angular momentum in oscillator ladder operators isEquivalently it is $-i\hslash (a_{1,+}{a}_{2,-}-a_{2,+}{a}_{1,-})$, consistent with the circular ladder operators of a two-dimensional oscillator.

Multiplying the quantum harmonic oscillator ground state by $x^2$ produces a quantum superposition of only its $n=0$ and $n=2$ energy eigenstates. In the conventional phase choice for the creation and annihilation operators, $X=\sqrt{\hslash /(2m\omega )}(b+b^{†})$ and $b|0⟩=0$. ThereforeAfter wavefunction normalization, the energy measurement probabilities are $1/3$ at $\hslash \omega /2$ and $2/3$ at $5\hslash \omega /2$. Rephasing the second basis state can change the displayed relative coefficient's sign but cannot change these probabilities. For example, defining the unscaled creation operator as $a_{+}=P+im\omega X=i\sqrt{2m\hslash \omega }{b}^{†}$ reverses the sign of the $n=2$ basis function generated from $(a_{+}{)}^2|0⟩$.

The quantum harmonic oscillator describes a particle of mass $m>0$ in a quadratic potential energy with angular frequency $\omega >0$. In the position representation its Quantum Hamiltonian isThe model is useful far beyond a literal spring: a Taylor series about a stable equilibrium with positive potential curvature has this quadratic term as its leading nonconstant approximation. The pure quartic oscillator has zero curvature at its minimum, so that particular approximation does not apply. ^[ref].

In units with $\hslash =1$, creation and annihilation operators giveHere $N$ is the number operator. Restoring the reduced Planck constant, the energy eigenvalues are $E_n=\hslash \omega (n+1/2)$ for $n=0,1,2,\dots$: neighboring levels are separated by $\hslash \omega$, and the ground-state energy is the zero-point energy $\hslash \omega /2$.

With length scale $\ell =\sqrt{\hslash /(m\omega )}$ and dimensionless coordinate $u=x/\ell$, the ground state is the normalized Gaussian wave packetFor $\hslash =m=\omega =1$, this is precisely the $a=1$ trial wavefunction in the quantum variational principle. The balance of kinetic energy and potential energy therefore recovers the exact ground-state energy using only Gaussian integrals.

A single-particle wavefunction used as a mode of a many-particle description. An orbital can include spatial and spin variables; a spatial orbital specifies the spatial part. Orthonormal orbitals define creation and annihilation operators. Occupation of one normalized orbital by every boson gives a Hartree product state, while antisymmetrized occupation by fermions gives a Slater determinant.

In the ideal electric-dipole interaction, a vibrational transition needs a nonzero matrix element of the electric dipole moment. For a diatomic bond stretch, expand the body-axis dipole component as $d(q)=d_e+d_e^{\prime }q+\cdots$. A changing electric dipole moment, rather than a permanent value $d_e$ alone, permits the harmonic fundamental. Keeping only the linear term and harmonic wavefunctions gives $\Delta v=\pm 1$.^[ref]

The derivation is sharper than a picture of a shaking molecule. Orthogonality removes the constant term for $v^{\prime }\ne v$, and creation and annihilation operators giveHere $\delta$ is the Kronecker delta. Thus absorption raises $v$ by one when the dipole derivative and angular factor are nonzero, and its photon satisfiesA nonzero vibrational matrix element is only one factor: rotational electric-dipole selection rules, initial populations, and spectral resolution also constrain visibility.

For an isolated diatomic molecule with identical atomic nuclei, such as molecular hydrogen in its symmetric electronic ground state, stretching preserves zero electric dipole moment. By symmetry, this homonuclear stretch is infrared inactive in the ideal dipole model, although it still vibrates. Other interactions or environments can permit detection.^[ref]