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An electric potential difference compares electric potentials at two points. For a move from $a$ to $b$, define $\Delta \Phi =\Phi (b)-\Phi (a)$; the terminal convention $V_{AB}=\Phi (A)-\Phi (B)$ instead means the potential at $A$ relative to $B$, so the order must always be stated. In electrostatics, the line integral of the electric field givesHere $\Delta U$ is the change in interaction potential energy of the test electric charge $q$ with fixed sources, while $W_{\mathrm{field}}$ is work done by the electric field. For an external agent moving the charge slowly without a change in kinetic energy, its work is $\Delta U$. A positive electric charge gains kinetic energy when accelerated toward lower electric potential; a negative electric charge gains kinetic energy when accelerated toward higher electric potential. Both motions lower $q\Phi$.^[ref]

For example, fix $Q=+2\mathrm{nC}$ at the origin and compare distances $r_a=0.20\mathrm{m}$ and $r_b=0.10\mathrm{m}$. With the stipulated approximation $k=8.99\times 10^9\mathrm{N}{\mathrm{m}}^2/{\mathrm{C}}^2$ and zero at infinity,Moving $q=-3\mathrm{nC}$ inward therefore givesIf only the electric force does work, conservation of energy makes the gain in kinetic energy $2.697\times 10^{-7}\mathrm{J}$. Direct integration confirms the signs: ${\int }_{r_a}^{r_b}kQdr/r^2=kQ(1/r_a-1/r_b)=-89.9\mathrm{V}$, which multiplied by the negative test electric charge gives positive work. The electric potential difference is unchanged by choosing a different electrical reference potential.

In an electrical circuit, an electric potential difference is the voltage across a component's terminals. In an electrical network, a vertex voltage is specified relative to a reference vertex; its differences across edges drive current flow. For a uniform electric field, the integral reduces to $\Delta \Phi =-\mathbf{E}\cdot ({\mathbf{r}}_b-{\mathbf{r}}_a)$. A field $\mathbf{E}=300V/m\hat{\mathbf{x}}$ across a displacement $0.04\mathrm{m}\hat{\mathbf{x}}$ therefore gives $\Delta \Phi =-12\mathrm{V}$, as in the interior approximation for a parallel-plate capacitor. The volt, measured in joules per coulomb, expresses energy transfer per unit electric charge, which makes it useful for comparing components without specifying the amount of charge transported.

Write $w_{xy}=w_{yx}>0$ for an edge conductance and $w_x={\sum }_{y\sim x}{w}_{xy}$. Take $s\ne t$, as implicit in a unit source-to-sink electrical network. An oriented current flow is antisymmetric, $i_{yx}=-i_{xy}$. Kirchhoff's first law is conservation of current: ${\sum }_y{i}_{xy}=0$ at every vertex other than the source and sink, with the divergences there equal to the prescribed total flow and its negative. Kirchhoff's second law says that the sum of oriented voltage drops around any closed cycle is zero. Ohm's law isThus the resistance of an edge is $1/w_{xy}$, and the cycle law reads ${\sum }_{j=0}^{m-1}{i}_{x_j{x}_{j+1}}/w_{x_j{x}_{j+1}}=0$ for $x_m=x_0$.

Let $\tau =\inf \{n\ge 0:X_n=t\}$. Its expectation is finite. Indeed, from each state there is a path to $t$ of length at most $|V|-1$ with positive probability; finiteness gives a common lower bound $a>0$ on reaching $t$ within that many steps. The Markov property then gives $\mathbb{P}(\tau >k(|V|-1))\le (1-a{)}^k$, proving the assertion. Define the expected occupation count before absorptionConditional expectation at every pre-stopping visit to $x$ gives ${\mathbb{E}}_s{N}_{xy}=G(s,x)p_{xy}$ for the number $N_{xy}$ of directed traversals. Hence the expected signed count isThis proves Ohm's law with voltage $v_x=G(s,x)/w_x$, grounded at $v_t=0$. Summing its voltage drops along a cycle telescopes, proving Kirchhoff's second law.

For Kirchhoff's first law, count entrances and exits on each stopped path. Their net difference at $x$ is the initial indicator minus the final indicator. Taking expectations,Thus the source emits exactly one unit, the sink receives one unit, and all other vertices conserve current.

We also establish the uniqueness required for the conclusion. The cycle law implies that edge voltage drops are differences of vertex potentials: define a potential by summing drops along a path to $t$, and cycle sums make this independent of the path. If two unit flows obey both laws, their difference has the form $j_{xy}=w_{xy}(h_x-h_y)$ with zero divergence at every vertex. ThereforeStrict positivity of the conductances and connectedness force $h$ to be constant, so $j=0$. We conclude the electrical current from stopped random-walk traversals identity

A voltage with boundary values $u(a)$ and $u(b)$ is a function $u:V\to \mathbb{R}$ that is harmonic at every other vertex:A current flow is an antisymmetric function $i(x,y)=-i(y,x)$ satisfying Kirchhoff's node law ${\sum }_{y}i(x,y)=0$ away from its source and sink. Voltage and current are related by Ohm's law,The effective resistance is the voltage drop divided by the total current from $a$ to $b$. Equivalently, it is the voltage drop generated by a unit current flow: