Equilibrium radiation and cavity frequencies. A blackbody absorbs all incident radiation at every frequency and direction. In thermal equilibrium its emission spectrum depends only on its temperature. Radiation inside an isothermal absorbing cavity, sampled through a small aperture that hardly disturbs equilibrium, realizes black-body radiation to a good approximation. Microscopic absorption and emission establish the equilibrium distribution; a perfectly reflecting wall is the convenient idealization used to count the modes once that distribution is specified.
In a rectangular electromagnetic cavity, the wave equation and perfect conductor wall boundary conditions select component wavenumbers , , . Combining the vacuum dispersion relation and gives
For example, electric-field components can have the spatial dependence
For three positive indices, Gauss's law requires , leaving two independent polarizations of an electromagnetic wave.
Index qualification. The original paper describes the indices as positive integers. That describes the three-nonzero-index family but omits valid electromagnetic modes with exactly one zero index, which have one polarization of an electromagnetic wave. For instance, with , , only above remains; it is normal to the top and bottom faces and vanishes at the side walls. Two zero indices give no nontrivial cavity field. The omitted one-zero-index family does not affect the leading three-dimensional mode count, but is essential to the thin-cavity limit below. Retaining the paper's strict positivity restriction for every mode would instead give a thickness gap and would not yield its requested two-dimensional power law.
Three-dimensional mode count. A lattice cell in positive space has volume , where . In a continuum approximation, a shell of radius and thickness contains its positive octant, multiplied by two polarizations:
Using gives
For a finite cavity the exact density of states is discrete; this formula is its bulk continuum limit, appropriate when many modes contribute and wall corrections are small.
Mean photon number. A mode is a quantum harmonic oscillator with thermal excitation energies , . The zero-point energy does not enter its thermal occupation. Put . Its partition function and mean occupation are
This is the Bose-Einstein distribution with zero photon chemical potential: equilibrium absorption and emission do not conserve photon number.
Thermal energy. Multiply the density of states by the mean excitation energy and integrate:
The substitution isolates all the dependence on cavity dimensions and temperature:
Expanding gives an integral . Hence
This is the thermal energy only, excluding the zero-point contribution. The three-dimensional continuum regime requires large compared with the geometric level spacings in all three directions.
Spectral sketch. The spectral energy density per unit ordinary frequency is Planck's law,
At small frequency it rises as , while at large frequency it decays exponentially. Raising temperature increases the spectrum at every fixed positive frequency, moves the peak to larger frequency in proportion to , and increases the integrated area in proportion to . A plot per unit wavelength has a different peak position because the integration variable changes.
Figure 1.
Planck spectral energy density at three temperatures on common frequency and energy-density scales
. Original plots of the frequency spectrum, with temperatures in the ratios 1:1.5:2. The dimensionless horizontal axis is hν/(kBTref), and the vertical scale is common to all curves. The higher-temperature peak moves right and the area grows as T to the fourth power. Details.
Thin-cavity radiation. Let . The relevant low-temperature window is
Nonzero thickness indices are then thermally suppressed, while many in-plane modes are populated. The family has one polarization of an electromagnetic wave. Its allowed in-plane wavenumbers form a lattice of cell area ; a quarter of a circular shell therefore contains
Thus the dimensional crossover of thermal cavity radiation gives
The integral is by the same geometric-series argument. A model with a different number of independent polarizations of an electromagnetic wave changes the prefactor but not the scaling. For a cavity with fixed finite , cooling still further eventually freezes its lowest in-plane mode as well: the strict thermal energy is exponentially suppressed. The requested area law is the intermediate quasi-two-dimensional regime, not an arbitrarily low-temperature continuum limit.