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The normalized wavefunction $\psi (x)=\sqrt{3}x/L^{3/2}$ on $(0,L)$ has sine coefficients $c_n=(-1{)}^{n+1}\sqrt{6}/(n\pi )$. Its ground-state probability is $6/{\pi }^2$, while its position probability in $(0,L/3)$ is $1/27$. The constant values of $E_n|c_n{|}^2$ make its energy expectation divergent. It is a valid Hilbert space vector but fails the finite-energy Dirichlet boundary-trace condition.

Write $k=\pi /a$, $A=\sqrt{2/a}$ and ${\Psi }_0=A{e}^{ikx}\sin kx$. Its derivative isIntegration by parts with the Dirichlet boundary conditions gives the energy expectationIt is constant in time, since the time-independent Hamiltonian operator has fixed energy measurement probabilities: $⟨H{⟩}_t={\sum }_n{E}_n|c_n{|}^2$.

For the midpoint parity operator, $R{\Psi }_0=-A{e}^{-ikx}\sin kx$. Hence, again putting $u=kx$,Indeed the imaginary part integrates to zero by reflection and ${\int }_0^{\pi }\cos 2u{\sin }^{2}udu=-\pi /4$. This expectation value is also constant in time, because the bounded self-adjoint operator $R$ commutes with $H$ and hence with its time-evolution operator. Equivalently, $⟨R{⟩}_t={\sum }_n(-1{)}^{n+1}|c_n{|}^2$.

For the momentum operator, direct evaluation givesThe real sine-cosine integral vanishes. This expectation value is not constant in time: the infinite square well walls reverse motion. One can prove the change exactly without approximating the wavefunction. Atthe energy eigenstate expansion and $R{\psi }_n=(-1{)}^{n+1}{\psi }_n$ give $\Psi (t_{\ast })=-R{\Psi }_0$. Differentiation shows $PR=-RP$, soThis half revival in an infinite square well is a concrete counterexample to momentum conservation. The sign from $-R$ is only a global phase.

The apparent interior identity $[H,P]=0$ cannot justify conservation here: the momentum operator does not preserve the Dirichlet boundary conditions of the Hamiltonian operator's operator domain. For sufficiently regular states, retaining the boundary terms in Ehrenfest theorem instead gives the boundary force in an infinite square well,In the strictly confined interval, $-i\hslash {\partial }_x$ with both endpoint values zero is symmetric but not itself a self-adjoint operator. The requested integral is the conventional mean momentum; it also equals the full-line momentum mean of the zero-extended state, as measured upon releasing the walls. This domain distinction explains why the formal interior commutator misses the wall force.

On a smooth wavefunction $f$, the position operator and momentum operator giveThus the canonical commutation relation is $\boxed{[X,P]=i\hslash I}$. Since $X$ and $P$ are self-adjoint operators and $m,\omega$ are real, the adjoint operator of $a_{-}$ isExpanding the products in the stated order is essential:Subtracting gives $\boxed{[a_{-},a_{+}]=2m\hslash \omega I}$. These identities initially hold on smooth rapidly decaying functions, which contain the quantum harmonic oscillator energy eigenstates used below.

The factorization also proves a lower bound: for a normalized energy eigenstate $H\psi =E\psi$,Therefore $E\ge E_0:=\hslash \omega /2$. The commutator product rule, applied to $H=a_{+}{a}_{-}/(2m)+E_0$, givesSo a nonzero application of the creation operator $a_{+}$ raises the energy eigenvalue by $\hslash \omega$, while the annihilation operator $a_{-}$ lowers it by the same amount.

Begin with any energy eigenstate, whose existence is assumed. Repeated lowering must terminate: otherwise it would eventually produce a nonzero energy eigenstate below $E_0$, contradicting the lower bound. More explicitly, if $(E-E_0)/(\hslash \omega )=N+r$ with integer $N\ge 0$ and $0\le r<1$, the first $N$ lowering steps are nonzero. If $r>0$, one further step is also nonzero by its positive squared norm and has energy $E_0+(r-1)\hslash \omega <E_0$, an impossibility. Thus $r=0$ and the last state satisfies $a_{-}{\psi }_0=0$. This provesEvery level exists as well: $\Vert a_{+}{\psi }_n{\Vert }^2=2m(E_n+\hslash \omega /2)=2m\hslash \omega (n+1)>0$, so repeated raising from ${\psi }_0$ never vanishes. The same factorization bounds the energy expectation of any normalized state in the one-dimensional harmonic oscillator form domain below by $E_0$, proving that the terminated state really is a ground state.

To find its probability density, solve the first-order equationIts solutions are ${\psi }_0=C_0\exp [-m\omega x^2/(2\hslash )]$. With $\alpha =m\omega /\hslash >0$, the supplied Gaussian integral givesTaking $C_0=(\alpha /\pi {)}^{1/4}$ fixes an irrelevant global phase. ConsequentlyThe ground-state energy is positive even though the potential minimum is zero: it is the oscillator's zero-point energy.

An energy measurement selects the ground state with probability equal to the squared inner product with ${\psi }_1$. Using $N=\sqrt{3}/L^{3/2}$ and integration by parts,ThusThe full Fourier sine series has $c_n=(-1{)}^{n+1}\sqrt{6}/(n\pi )$, so ${\sum }_n|c_n{|}^2=(6/{\pi }^2){\sum }_n{n}^{-2}=1$, an independent wavefunction normalization check. However $E_n|c_n{|}^2=3{\hslash }^2/(m{L}^2)$ for every $n$, hence ${\sum }_n{E}_n|c_n{|}^2$ diverges. This explicitly verifies the infinite-energy expectation qualification in part (b), without invalidating the individual projection probabilities.

A sudden wall displacement leaves the initial wavefunction unchanged: it is $\sqrt{2/L}\sin (\pi x/L)$ on $[0,L]$ and zero on $(L,2L]$. It is not an eigenfunction of the new Hamiltonian, so there is no single certain new energy. Its energy expectation immediately afterward remains $E_1^{\mathrm{old}}$, as seen from ${\hslash }^2\int |{\psi }^{\prime }{|}^2/(2m)$; the measurement outcomes are $E_n^{\mathrm{new}}=n^2{E}_1^{\mathrm{old}}/4$.

The new ground state is $L^{-1/2}\sin (\pi x/(2L))$. Its overlap is $4\sqrt{2}/(3\pi )$, soThe discontinuity of the derivative at the former wall does not invalidate the finite quadratic-form expectation, although it matters when applying the differential Hamiltonian pointwise. Adiabatic expansion would instead keep the state in the ground level and reduce its energy by four.

In a well $-a<x<a$, the normalized state proportional to $x$ on $0<x<a$ and zero elsewhere has stationary-state coefficients in the normalized energy eigenfunction basis ${\varphi }_n(x)=a^{-1/2}\sin [n\pi (x+a)/(2a)]$, with $n=1,2,\dots$,They follow from the orthonormal basis inner products. Their squared magnitudes give energy-measurement probabilities by the Born rule; splitting even and odd indices in the Parseval identity gives convergent integer-coefficient series identities. The expansion is interpreted in the square-integrable state norm.

Here the wavefunction is $\sqrt{3}x/a^{3/2}$ for $0<x<a$ and zero for $-a<x<0$. Its nonzero trace at the right wall means it is a valid square-integrable state with divergent energy expectation, as in the linear ramp state in an infinite square well.