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An atmospheric retrieval fits a parametrized radiative transfer model to an exoplanet transmission spectrum or exoplanet emission spectrum. Temperature, abundances, clouds and reference radius/pressure can trade off against one another. Posterior precision within one model is not proof that its structural assumptions are unique.

Assume $R_p/R_{\star }=0.10$, $T_{\star }=5800\mathrm{K}$, uniform disk-averaged thermal emission, a nearly blackbody stellar continuum, negligible reflected light at $20\mu \mathrm{m}$, and a flat response over the narrow band. If the eclipse depth is normalized to the out-of-eclipse star-plus-planet flux, the planet/star flux ratio is $r=0.005/(1-0.005)=0.005025$; using $r=0.005$ changes the estimate by less than one percent. The exoplanet secondary eclipse then givesUsing the Planck law at $\lambda =20\mu \mathrm{m}$ gives $T_1\simeq 3.1\times 10^3\mathrm{K}$, or about $3000\mathrm{K}$ at the precision justified by the radius assumption. The Rayleigh-Jeans law instead gives $T_1\simeq 0.5T_{\star }\simeq 2900\mathrm{K}$, a useful rough check. This is a brightness temperature, not the bolometric planetary equilibrium temperature. With zero Bond albedo and global redistribution, the latter would be only about $1250\mathrm{K}$ at $0.05\mathrm{AU}$; a thermal window can sample hotter, deeper gas.

A continuum photon normally emerges from an optical depth of order unity. In hydrostatic equilibrium,The emission-pressure degeneracy of a brightness temperature means that pressure cannot be uniquely recovered from the measured brightness temperature without $g$ and an opacity model. For an explicit nominal estimate, take $g=20\mathrm{m}{\mathrm{s}}^{-2}$ and an effective continuum mass absorption coefficient ${\kappa }_{20}=2\times 10^{-4}{\mathrm{m}}^2\mathrm{k}{\mathrm{g}}^{-1}$. Then $P_{\tau \sim 1}\sim g/{\kappa }_{20}=10^5\mathrm{Pa}$, or approximately one bar. In a hydrogen-rich atmosphere, collision-induced absorption by transient ${\mathrm{H}}_2$ pairs supplies continuum opacity even without ordinary molecular lines; its density dependence makes the constant-opacity calculation an illustrative estimate. With a normal deep atmospheric pressure-temperature profile, temperature increases at larger pressures, eventually following an interior adiabatic temperature gradient.

Two mechanisms for $T_1\ne T_2$ are wavelength-dependent sampling of a vertically varying temperature, and wavelength-dependent weighting of a horizontally nonuniform dayside. In the first, carbon monoxide-rich opacity near $4.5\mu \mathrm{m}$ can sample cooler gas around $0.1$ bar while the $20\mu \mathrm{m}$ continuum samples hotter gas around one bar. In the second, hot and cool areas contribute different proportions of the total flux in different bands because the Planck function depends nonlinearly on temperature. The vertical mechanism alone produces the illustrated pair of temperatures; a single isothermal, horizontally uniform blackbody would have the same brightness temperature in both bands.

If the J-band observation is thermal emission, its low-opacity window normally samples at least as deeply as the continuum at $20\mu \mathrm{m}$. On the illustrated non-inverted profile, $T_3\gtrsim T_1>T_2$. The ordering is conditional: molecular-line absence alone does not specify the relative continuum opacities, and an inversion or reflected-light contamination can change the inference. The exoplanet emission spectrum measures weighted contribution regions rather than three exact thermometers at known pressures.

The spherical stellar structure equations apply to a planet as well, with its appropriate equation of state:The last equation is the local first law, including gravitational contraction through the specific entropy change. For an isolated non-burning planet, ${ϵ}_{\mathrm{nuc}}\simeq 0$, soIf the convective interior has nearly uniform specific entropy $s(t)$, positive outgoing luminosity gives $\dot{s}=-L_{\mathrm{int}}/\int Tdm<0$. This entropy loss of an isolated convective planet describes its secular cooling.

During assembly, the gravitational energy scale $G{M}^2/R$ provides a source of heat. Integrating hydrostatic equilibrium gives the virial theorem, $\Omega +3\int PdV=0$, neglecting the surface-pressure term. For a monatomic ideal gas this becomes $2U+\Omega =0$, hence $E=U+\Omega =\Omega /2$. Contraction makes $\Omega$ more negative, releases radiation, and heats part of the gas. A characteristic formation temperature has scale $k_{B}T\sim \mu m_{H}GM/R$ up to structure factors. The retained fraction depends on the accretion shock, producing hot and cold starts of a giant planet.

Formation releases heat, and an isolated planet subsequently loses specific entropy and intrinsic luminosity as it approaches a cooler, more degenerate state. The structure equations alone do not fix one initial temperature, and the early contraction of an ideal gas can increase its central temperature while its total energy decreases. “Cools” therefore need not mean that every depth becomes colder at every instant. Once degeneracy limits contraction, the thermal reservoir declines more directly; the emergent effective temperature usually falls along a fixed-mass cooling track.

This makes young giant planets attractive for exoplanet direct imaging: their thermal near/mid-infrared emission can be far brighter than that of old planets of the same mass. Imaging and spectroscopy measure projected separation, astrometry, luminosity, an exoplanet emission spectrum, temperatures and atmospheric molecular and exoplanet cloud signatures. Radius follows from luminosity and fitted temperature; mass and initial specific entropy generally require age/evolutionary information, or an independent dynamical mass measurement. A detected luminosity alone is not a model-independent planet mass.

A natural interpretation of the short-wavelength peak is reflected starlight, while the longer-wavelength peak is planetary thermal radiation. A reflected spectrum approximately follows the stellar spectrum multiplied by the wavelength-dependent geometric albedo; thermal radiative flux approximately follows the planet's Planck function, modulated by molecular opacity. Thus two peaks need not represent two planetary surface temperatures.

For a quantitative estimate assume both are broad $F_{\lambda }$ peaks, reflection has a slowly varying geometric albedo, and star and planet have approximately blackbody spectral envelopes. Wien's displacement law then givesThe stellar estimate is compatible at order of magnitude with an old, relatively small main-sequence star; equal age does not mean equal temperature to the Sun. Assume the far-infrared signal is thermal and sufficiently long-wavelength that the Rayleigh-Jeans law applies to both bodies. The planet-star radius estimate in the Rayleigh-Jeans limit givesand thereforeThis is a small volatile-rich-planet-sized estimate, not a Jupiter-sized one. It is conditional: peaks caused by molecular windows, strongly chromatic reflection, or a spectrum expressed as $F_{\nu }$ rather than $F_{\lambda }$ do not support those two Wien estimates. Without $T_p/T_{\ast }$, the far-infrared ratio only fixes $R_p^2{T}_p/T_{\ast }$.

For a close-in hot planet around a small star, transit-based atmospheric observations are the natural route if the orbital geometry allows them. Exoplanet transmission spectra gain from the small stellar radius, with a limb signal scaling as $2R_{p}H/R_{\ast }^2$; they probe composition at the day-night terminator. The stated $10^{-3}$ thermal contrast also makes exoplanet secondary eclipse measurements a particularly useful route to the dayside exoplanet emission spectrum. Resolving such a close-in small planet by exoplanet direct imaging is much harder. Transit and secondary-eclipse spectroscopy are favoured for a transiting close-in interpretation; the supplied spectrum alone does not determine the orbital geometry or a unique best technique.

The two measurements sample different atmospheric regions and different radiative transfer geometries. An exoplanet emission spectrum probes the dayside; an exoplanet transmission spectrum probes the morning and evening limbs of the day-night terminator. Several alternatives to an exoplanet cloud deck can therefore suppress the transmission feature.

Temperature, mean molecular weight, limb chemistry, continuum opacity and the dayside temperature gradient are alternatives or degeneracies to test. In particular, the three-scale-height amplitude alone cannot establish different CO abundances between the hemispheres.

Four possible molecular signatures of disequilibrium chemistry in an exoplanet atmosphere, measured through an exoplanet transmission spectrum or exoplanet emission spectrum, are:

The first two signatures can be consequences of the same process and are not independent evidence for two mechanisms. Changes in atmospheric carbon-to-oxygen ratio, atmospheric metallicity of a giant planet, exoplanet cloud coverage, and the atmospheric pressure-temperature profile can mimic abundance changes. A convincing inference compares several molecular bands with a chemically consistent equilibrium model rather than identifying one unusual band alone.

Three major research directions, appropriate to the scientific questions posed in 2018, are:

These are research goals rather than claims that the relevant mechanisms or habitable atmospheres have already been established.

Exoplanet clouds and atmospheric haze add scattering and absorption opacity to an exoplanet transmission spectrum. A high opaque deck truncates the slant path and mutes molecular bands, while small aerosol particles can produce a blue scattering slope; patchiness creates mixtures of clear and cloudy limbs. In an exoplanet emission spectrum, aerosols move the photosphere to lower pressure, weaken or reshape molecular features, alter the geometric albedo, and can heat or cool layers depending on their shortwave and longwave absorption.

Observed aspects of exoplanet atmospheric dynamics include eastward equatorial atmospheric superrotation inferred from shifted thermal hot spots, day-night heat transport measured by phase-curve amplitude, and high-altitude winds measured from Doppler shifts of resolved spectral lines. Time-variable phase curves and eclipse maps also reveal changing cloud patterns and storms.

The measured mass and radius illustrate the exoplanet interior-composition degeneracy. Three plausible structures are:

An exoplanet transmission spectrum can distinguish a large-scale-height hydrogen atmosphere from compact steam or carbon-dioxide atmospheres. Molecular abundances, clouds, atmospheric mean molecular mass, and atmospheric escape constrain the envelope mass and evolution. An exoplanet emission spectrum constrains temperature, albedo, and internal cooling. A detected hydrogen-rich atmosphere favors the first scenario, a water-dominated high-molecular-weight spectrum supports the second, and a thin secondary atmosphere supports the third, although clouds can preserve degeneracies.