Take positive to mean net removal of thermal energy per unit mass. The isobaric thermal stability of a heated ideal gas depends on the density change accompanying a temperature disturbance. For an ideal gas of fixed composition, , so constant pressure gives . Therefore the net cooling can be written
where is constant for this pressure. At thermal equilibrium , .
The first law of thermodynamics at constant pressure includes the expansion work, so the relevant heat capacity is the specific heat capacity at constant pressure, , rather than the constant-volume value. Linearizing its temperature equation gives
Hence
For optically thin Bremsstrahlung, , so
A hotter parcel expands and becomes less dense. Its cooling per unit mass, proportional to at fixed pressure, decreases while its cosmic ray heating stays fixed, making it hotter still. A colder, denser parcel cools faster and runs away in the opposite direction. Here has units and units , so is an inverse time. The conclusion assumes the disturbance remains close to pressure equilibrium and neglects heat conduction and changes of composition. The relevant is the temperature exponent in the supplied cooling law.