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For harmonic electric fields with time convention $e^{i\omega t}$, write $\mathbf{D}={ϵ}^{\ast }(\omega )\mathbf{E}$ for their complex amplitudes, where $\omega$ is angular frequency. The real part ${ϵ}^{\prime }$ describes the in-phase electric displacement field; the minus imaginary part ${ϵ}^{\prime \prime }$ describes the loss component. The sign reverses with the opposite time convention. Complex permittivity can also be a tensor in a linear anisotropic dielectric.

Because ${\epsilon }_{ij}$ and ${\mu }_{ij}$ are symmetric and time-independent, the linear anisotropic dielectric relations giveand similarlyIntegrate the identity from part (b) over $V$ and apply the divergence theorem to obtainWhen $\mathbf{J}=0$, this is conservation of electromagnetic energy. The Poynting theorem in a linear anisotropic medium identifiesas the energy density andas the energy flux, or Poynting vector.

Permittivity describes how an electric field and a material's electric polarization combine into the electric displacement field. In a static, local response with linearity and isotropy, and no electric polarization at zero electric field, the constitutive equation isHere ${ϵ}_0$ is vacuum permittivity, while ${ϵ}_r$ is the relative permittivity, a dimensionless quantity. The SI unit of permittivity is farad per metre, $F/m$: multiplying it by an electric field in $V/m$ gives an electric displacement field in $C/{\mathrm{m}}^2$. A larger positive permittivity lets the same parallel-plate capacitor hold more plate electric charge at the same electric potential difference.

The material contribution is electric polarization $\mathbf{P}$, the electric dipole moment per unit volume. The electric displacement field and electric susceptibility ${\chi }_e$ satisfySubstitution gives the first constitutive equation. The electric field here is the averaged, total field inside the material, not just the field of the external plate electric charges. The continuum approximation averages over many chemical atoms or molecules; locality means that the electric polarization at a position depends on the electric field there. Static equilibrium, fixed material conditions and sufficiently small electric fields are needed for this scalar proportionality. ^[ref].

For an ideal parallel-plate capacitor completely filled by a uniform dielectric, hold the free plate electric charge magnitude $Q$ fixed and neglect the fringing field of a capacitor. Writing $A$ for the plate area, Gauss's law gives $D=Q/A$. ThusThe electric dipoles point along the electric field. Their surface electric charges, described by polarization density, oppose the field from the free plate electric charges. For a hypothetical dielectric with ${ϵ}_r=4$, the internal electric field is one quarter of its vacuum value, while $P=3D/4$. At fixed electric potential difference instead, the internal electric field stays approximately $V/d$ and the plate electric charge grows fourfold. These are different experimental constraints. ^[ref].

Permittivity is a useful material summary, not a universal constant of the material under every condition. Temperature, frequency and electric field strength can change the response. In a linear anisotropic dielectric, permittivity is a tensor, $D_i={\sum }_j{ϵ}_{ij}{E}_j$, so the electric displacement field need not be parallel to the electric field. At nonzero frequency, delayed electric polarization requires complex permittivity and may produce dielectric loss. ^[ref].

A transparent, nonmagnetic linear anisotropic dielectric is uniaxial when two principal permittivities agree. With the optic axis along $z$, its permittivity tensor has the displayed diagonal matrix form. Here $n_o$ and $n_e$ are principal refractive indices at a specified frequency; $n_e$ is not the extraordinary wave's index in every direction.^[ref]