Extraordinary wave ($n_{\mathrm{ex}}(\theta )$)

The extraordinary wave's electric displacement field lies in that plane and is perpendicular to the wavevector; its electric field need not be. For angle $\theta$ between the wavevector and optic axis,Thus $n_{\mathrm{ex}}(0)=n_o$ and $n_{\mathrm{ex}}(\pi /2)=n_e$.^[ref]

A short derivation starts from the existing plane wave in an anisotropic dielectric equation. Put $\mathbf{k}=(k_x,0,k_z)$ and $k_0=\omega /c$, with angular frequency $\omega$ and vacuum speed of light $c$. The $y$ component gives the ordinary wave relation $k_x^2+k_z^2=n_o^2{k}_0^2$. The determinant of the $x,z$ system givesSubstituting $k_x=n_{\mathrm{ex}}{k}_0\sin \theta$ and $k_z=n_{\mathrm{ex}}{k}_0\cos \theta$ yields the displayed directional refractive index.

The extraordinary wave's Poynting vector can differ in direction from its wavevector. The latter specifies wave phase propagation, while the former specifies energy flux. This angular separation is walk-off.^[ref]

In the lossless, nondispersive model above, take the gradient of $\omega =c\sqrt{k_x^2/n_e^2+k_z^2/n_o^2}$ to obtain the group velocity, parallel to the Poynting vector. If its angle to the optic axis is $\varphi$, this gives $\tan \varphi =(n_o^2/n_e^2)\tan \theta$. Consequently the extraordinary wave generally carries energy away from its wavevector direction. An internal wavevector normal to a slab face therefore does not guarantee a normal energy path. Birefringent walk-off vanishes at $\theta =0$ and $\theta =\pi /2$; the latter direction still has unequal refractive indices. This is a useful waveplate geometry: overlapping components can acquire phase retardation without spatial splitting. A thin specimen, insufficient imaging resolution, or excitation of only one linear polarization can also hide a double image, for different reasons.

For a lossless nonmagnetic uniaxial optical medium, the electric displacement field of a plane electromagnetic wave is perpendicular to its wavevector. The magnetic field is perpendicular to the plane containing the electric field and wavevector, while the Poynting vector is perpendicular to the electric field in that same plane. Thus the angle between $\mathbf{E}$ and $\mathbf{D}$ equals the walk-off angle between energy flow and phase propagation. At normal incidence on a parallel slab of thickness $L$, a lateral separation $\Delta$ of the ordinary and extraordinary exiting rays gives ${\alpha }_e=\arctan (|\Delta |/L)$, while ${\alpha }_o=0$. The output rays can be parallel even though their internal energy paths differ.