Using the given linear momentum balance, multiply by the velocity and integrate over the fixed volume:This is integration by parts component by component, or the divergence theorem. The first term is boundary stress power. With component-first velocity gradient , the second is the double contraction .
For a Newtonian fluid, , where is the rate-of-strain tensor and is dynamic viscosity. Incompressibility removes the pressure contribution, and the symmetric tensor is orthogonal to the antisymmetric part of . ThereforeThe displayed energy identity follows for the stated linear balance. A full advective momentum equation in a fixed control volume would also contribute an advective kinetic energy flux. The nonnegativity statement here is for a purely Newtonian viscous stress; a viscoelastic stress can exchange stored free energy with the flow.
Let , , and . The configuration equation of the Hookean dumbbell model becomesHere the paper's denotes the Boltzmann constant . Integrating the second moment equation against and discarding boundary terms at infinite separation givesFor example the spring drift differentiates each factor , while the Laplacian gives . The Hookean dumbbell conformation equation isIn the row-vector convention of , the displayed gradient tensor is , giving exactly the transposes in the requested equation. The dimensionless conformation tensor consequently has upper-convected derivative , with polymer relaxation time . This normalization matters: the unscaled has equilibrium value , rather than .
Write the centre position as and the bead positions as . In the affine velocity field, . The midpoint follows the flow, so its two slip velocities areEach bead loses mechanical power times its squared slip speed. Adding the two powers proves the drag dissipation of a bead-spring pair:The factor one half comes from two equal-and-opposite bead slips, not from assigning only one bead a drag force.
The claimed equality does not hold for the printed joint distribution. The original PDF specifies a centered Maxwell-Boltzmann distribution of independent of , withSince the double average includes number density , evaluating the Gaussian integrals givesThe cross term vanishes because the conditional mean of is zero. In particular, set and take the equilibrium configuration probability density . The left side is , while . This is a counterexample even at thermal equilibrium, so no rearrangement of the earlier conformation tensor equation can prove the printed statement.
The discrepancy is thermal bead drag and heat-bath power: gross viscous loss of microscopic thermal motion is replenished by the thermal bath. It is not identical to mechanical polymer stress power. Moreover, in the earlier configuration continuity equation is a probability current velocity, including a distribution-dependent osmotic drift; it cannot simultaneously be identified with an independently sampled centered Maxwellian velocity.
A consistent overdamped result is the free-energy balance of a Hookean dumbbell. Define andDifferentiate the relative entropy and use the configuration Fokker-Planck probability current . After integration by parts,The affine osmotic term is . HenceThe polymer stress tensor has in an incompressible flow. It stores or releases free energy as well as dissipating it, so the total stress-work term in part a need not itself be a purely dissipative quantity for this viscoelastic material. Stress power equals only for stationary free energy, and uses the probability-current slip. Neither condition turns the printed independent-Maxwellian average into that expression.
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