The normalized quantum harmonic oscillator ground state has and energy . Its classical turning points are . With , the ground-state oscillator probability beyond the turning points isThe stated rounded error function gives ; the more precise Gaussian integral is .
An impulse integrated across its full support produces the impulsive quantum kick . Thus the leading transition amplitude is andHere has units of action. The off-diagonal two-state impulse is exactly for a Hermitian two-state impulse with zero diagonal. No energy denominator occurs: the impulse is instantaneous.
For two equivalent electrons, antisymmetry permitsTheir states exhaust . Hund's rules first maximize spin, then orbital angular momentum; the less-than-half-filled shell puts the smallest lowest. Hence the ground level is . This is the allowed LS terms of a p-squared configuration.[ref]
Energy Levels of Neutral Carbon by National Institute of Standards and Technology. Ground configuration2s²2p² and its³P,¹D,¹S levels
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