For low temperature, factor out the largest Boltzmann factor from the dominant eigenvalue:Thus the Helmholtz free energy per site has the expansionDifferentiate at fixed , remembering that . The entropy per site isThe nonzero residual entropy comes from an exponentially large ground-state degeneracy, generated by geometrical frustration. A triangle with antiferromagnetic energy has minimum energy : if , the apex must have the opposite sign; if , either apex sign is permitted. The two all-equal configurations instead have energy . Thus exactly one of a minimum-energy triangle's bonds is frustrated. The bridge can simultaneously minimize its energy at by requiring , where is the next cell's first base spin.
For fixed and , the number of allowed apex choices is therefore two when and one when . The zero-temperature counting transfer matrix on successive first base spins isThe eigenvalues of are and . Dividing by the sites and taking the thermodynamic limit gives , independently confirming the derivative calculation. This does not assert a unique ordered ground state: the extensive choice of frustrated bonds is precisely what leaves entropy at zero temperature. At high temperature, all Ising spins become independent and per site.
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