For bulk electric-dipole second-harmonic generation, the crystal must lack inversion symmetry and have a nonzero relevant component of its second-order nonlinear optical susceptibility. It should transmit both pump and harmonic, tolerate the required intensity, and allow phase matching by suitable birefringence or another phase-compensation mechanism. A large nonlinear coefficient, low optical loss and good optical quality are desirable. Noncentrosymmetry permits a response but does not guarantee one in every chosen geometry.
In the undepleted plane wave limit, contributions from successive layers give a harmonic amplitude proportional to , where . HenceTune orientation, temperature and pump polarization to maximize the nonlinear coupling and cancel phase mismatch. For continuous operation, an impedance-matched enhancement optical resonator, or intracavity doubling, raises the circulating intensity. Focus the Gaussian beam to balance intensity against diffraction and spatial walk-off; arbitrarily tight focusing shortens the useful overlap. Antireflection surfaces, stable resonance locking and efficient heat removal reduce avoidable loss and drift.
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