For a quantitative thermal-relic prediction, assume one ordinary weakly interacting neutrino flavor: one populated neutrino helicity and one antineutrino helicity, negligible chemical potential, early thermal equilibrium, and relativistic decoupling around the MeV epoch. Equal neutrino and antineutrino populations imply no new lepton asymmetry. The Fermi-Dirac distribution is maintained while the weak interaction rate exceeds the expansion rate. After neutrino decoupling, the distribution free streams, its momentum scale falls as , and its comoving number is conserved. A mass of is negligible at Big Bang nucleosynthesis temperatures, but the relic later becomes nonrelativistic. Its energy density then changes from radiation-like scaling to matter-like scaling. Stability prevents its removal by decay; decoupling while relativistic prevents a subsequent equilibrium Boltzmann suppression of its number.
Before electron-positron annihilation in cosmology, the pair has two spin states, just as photons do, and the fermionic number integral gives at equal temperature. The factor follows by expanding into an alternating exponential series: its integral is of the bosonic one.
After neutrino decoupling, cosmological entropy conservation in the photon-electron plasma changes its relativistic entropy count from to . The decoupled neutrinos do not share this heating. HenceThese counts include both the new neutrino and its antineutrino; another factor of two would double count them. This is the number density of a relativistic neutrino relative to photons, evaluated after photon heating.
They are nonrelativistic today, so the relic-neutrino energy density is dominated by rest mass:The number follows from the supplied critical density, without a Hubble-unit convention. It is conditional on the thermal history stated above; a sterile, colder or nonthermally produced state need not have this abundance.
At weak freeze-out, photons, electrons, positrons and all four neutrino flavors are relativistic and approximately at the same temperature. The effective number of relativistic energy degrees of freedom changes fromThe expansion rate at fixed temperature is larger by . Equating the supplied weak interaction time with the supplied age gives when is measured in MeV. ThereforeEarlier cosmological weak freeze-out at a higher temperature leaves more neutrons. With negligible chemical potentials, the neutron-to-proton ratio in equilibrium is , where . If almost all surviving neutrons enter helium-4, the primordial helium mass fraction before neutron decay is . Literal use of the given rate normalizations yieldsEquivalently, the leading response is . This is a roughly one-percentage-point absolute increase in the helium fraction, rather than a one-percent relative increase.
The deuterium bottleneck delays nuclear burning, allowing free-neutron decay after freeze-out. If its end temperature is , and is the neutron mean life, a sharper instantaneous-freeze-out estimate conserves total baryon number and givesThis formula evolves the neutron fraction, not just the neutron-to-proton ratio, because each neutron decay also creates a proton. After electron annihilation, let . The radiation counts relevant to the age at fixed areConsequently . Less time is available for neutron decay, adding to the helium increase. As an explicit illustrative completion, and give an increase of approximately in this toy model. The precise helium fraction requires the nuclear-burning temperature, baryon abundance and properly normalized weak rates; the question supplies only approximate time laws. In particular, the large no-decay fractions in the table must not be interpreted as precise predictions for the observed primordial abundance. The robust effect is extra relativistic energy raises the primordial helium fraction, with an absolute change of order for one thermally populated flavor.
The density bound on a relativistically decoupled massive relic is already decisive for a conventional near-critical cosmological density budget: the thermal pair alone gives . The same additional relativistic pair increases the effective number of neutrino species by one during nucleosynthesis and raises the primordial helium mass fraction, so its expansion effect supplies another constraint. Thus a stable, fully thermalized MeV-decoupling neutrino pair of this mass is incompatible with the usual cosmological density budget.
This conclusion is not a prohibition on every particle with that mass. Earlier decoupling followed by entropy dilution, a reduced production abundance, or interactions that change the assumed thermal history can alter both tests. At fixed mass, requiring this pair to contribute no more than the supplied critical density would demand a number density at most of the standard value, or a thermal temperature at most of the standard neutrino temperature. No numerical abundance or exclusion independent of these assumptions follows from the mass and equal particle-antiparticle counts alone.
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