Primordial helium mass fraction

If almost all neutrons enter helium-4 and $r=n_n/n_p$, its primordial mass fraction is $Y_p\simeq 2r/(1+r)$.

At fixed cosmological weak freeze-out temperature $T_f$ and fixed neutron survival factor, neutron-proton chemical equilibrium gives $r_f=e^{-Q/T_f}$ and neutron-limited helium synthesis gives $Y_p\propto 2r_f/(1+r_f)$. Differentiating yields the displayed sensitivity. A finite change $Q\mapsto (1+\alpha )Q$ gives $Y_p^{\prime }/Y_p=(1+e^{Q/T_f})/(1+e^{(1+\alpha )Q/T_f})$. Increasing the positive mass difference reduces helium production. Changes to the weak conversion rates, neutron lifetime or nuclear history must be supplied separately for a full abundance prediction.

After cosmological weak freeze-out, the surviving neutron fraction is $x_n=r_f(1+r_f{)}^{-1}{e}^{-\Delta t/{\tau }_n}$, where $r_f$ is the initial neutron-to-proton ratio and ${\tau }_n=t_{1/2}/\ln 2$ is the mean lifetime. Baryon number is conserved because a decaying neutron becomes a proton. If almost all surviving neutrons enter helium-4, neutron-limited helium synthesis gives the displayed primordial helium mass fraction. Increasing the half-life increases survival. If the longer lifetime also represents uniformly weaker weak interactions, it raises the temperature of cosmological weak freeze-out and the initial neutron fraction, reinforcing the helium increase. That last conclusion requires specifying how the weak rates change, rather than treating lifetime alone as a complete microscopic model.

With a weak conversion time proportional to $T^{-5}$ and a radiation-era age proportional to $g_{\ast }^{-1/2}{T}^{-2}$, cosmological weak freeze-out occurs at $T_f\propto g_{\ast }^{1/6}$. Extra radiation therefore raises the freeze-out temperature and the neutron-to-proton ratio $r_f=e^{-Q/T_f}$. Before decay, the primordial helium mass fraction is $Y_f=2r_f/(1+r_f)$, giving $\delta Y_f/Y_f=Q\delta \log T_f/[T_f(1+r_f)]$. A shorter delay through the deuterium bottleneck also leaves more neutrons. After freeze-out, conserve baryon number and evolve the neutron fraction to obtain $Y_p\simeq Y_f{e}^{-(t_N-t_f)/{\tau }_n}$. A precise abundance requires the weak rates and nuclear-burning history, not merely the number of relativistic species.

Chemical equilibrium of $n+{\nu }_e\leftrightarrow p+e^{-}$, with negligible electron chemical potential, gives the stated neutron-to-proton ratio. Positive electron-neutrino degeneracy reduces the neutron fraction, whereas negative degeneracy increases it. The primordial helium mass fraction then responds through neutron-limited helium synthesis while protons outnumber neutrons; a sufficiently neutron-rich mixture instead becomes proton limited, so that trend must not be extrapolated indefinitely. Extra neutrino energy density also accelerates cosmic expansion, changing weak freeze-out and the time available for neutron decay. These effects can compete; a quantitative Big Bang nucleosynthesis calculation must account for the altered reaction rates as well as the altered expansion rate.

When protons outnumber neutrons, helium-4 production is neutron-limited and produces about one helium nucleus per two neutrons.

During radiation domination, the weak conversion rate scales as $T^5$ whereas the Hubble parameter scales as $\sqrt{G{g}_{\ast }}{T}^2$. Their crossing fixes the cosmological weak freeze-out temperature. A faster expansion raises it, leaving a larger neutron-to-proton ratio, and shortens the interval for free-neutron decay after freeze-out. Both effects increase the helium-4 mass fraction if the extra component does not independently change reaction rates or inject decay products.

If the Friedmann equation remains approximately $H^2=8\pi G\rho /3$, radiation domination and fixed weak microphysics give $H\propto \sqrt{G}{T}^2$ and a neutron-proton conversion rate proportional to $T^5$. Cosmological weak freeze-out then occurs at $T_f\propto G^{1/6}$. Increasing $G$ during this era raises the neutron-to-proton ratio at freeze-out and shortens the time for free-neutron decay after freeze-out. Both increase the primordial helium mass fraction when neutron-limited helium synthesis remains efficient. Arbitrary variation of $G$ over time requires its history and the full gravitational field equations; this scaling is a controlled background approximation, rather than a complete model of gravity with arbitrary time dependence.

A moderately enhanced Hubble parameter raises the primordial helium mass fraction through earlier cosmological weak freeze-out and less free-neutron decay after freeze-out, provided nuclear burning still incorporates nearly all surviving neutrons into helium-4. This provision matters: if expansion carries the gas through the nuclear-burning temperature range faster than the reaction times, neutron-limited helium synthesis no longer applies. More neutrons surviving the bottleneck alone does not prove more final helium in that limit.

Increasing primordial helium at the expense of hydrogen reduces fuel for long-lived main-sequence hydrogen burning and changes subsequent stellar evolution.