A ground-state baryon contains three quarks in a spatially symmetric wavefunction, giving positive parity. Each quark is a spin one-half fermion, so the complete wavefunction must be antisymmetric under interchange of its complete quark labels. A physical baryon is a colour singlet, with the antisymmetric colour factorConsequently the combined spin-and-flavour factor must be symmetric. The product notation in the question organizes the degrees of freedom; it need not mean that spin and flavour are separately unentangled. In particular the octet requires a correlated sum of products.
For the three light flavours, the flavour symmetry decomposition isThe subscripts describe permutation symmetry, with denoting mixed symmetry. The addition of angular momentum of three spin one-half particles givesThe symmetric spin quartet has total ; the two spin doublets have .
For , the spin factor is symmetric, so the flavour factor must also be symmetric: this gives the spin- baryon decuplet. Its flavour content is four states, three states, two states, and one state.
For , the mixed-symmetry spin functions combine with the mixed-symmetry flavour functions to make one fully symmetric spin-flavour factor for each octet weight: this gives the spin- baryon octet, containing two nucleons, three Sigma baryons, one Lambda baryon, and two Xi baryons. The two mixed-symmetry octets in the raw flavour product are not two distinct ground-state octets; their permutation partners are correlated with the spin factors. An antisymmetric flavour singlet would require a fully antisymmetric spin factor to make a symmetric product, but three spin states drawn from a two-dimensional single-quark spin space have no such factor.
Equivalently, the symmetric three-particle representation of spin-flavour symmetry has dimension and decomposes under flavour and spin intoThese are approximate multiplets: the larger strange quark mass breaks exact flavour symmetry and splits their energies.
The baryon hyperfine mass formula is a phenomenological constituent-quark model. The three constituent quark masses include effects of strong-interaction dressing and an approximate spin-independent confinement energy; they are not the small running quark masses in a short-distance Quantum chromodynamics calculation.
The residual correction has the form of a colour-magnetic spin-spin interaction. A nonrelativistic reduction of one-gluon exchange produces a contact contribution proportional toAfter taking its expectation in the common spatial wavefunction and the colour singlet, the colour factor, coupling, and contact density are absorbed into . Summing the three quark pairs gives the supplied formula. Positive raises aligned-spin configurations relative to lower-spin configurations. In natural units, the spin angular momentum operators are dimensionless, so has units of energy cubed, as in the given .
Label the identical strange quarks as 1 and 2 and the up quark as 3. In the ground spatial state, the pair has symmetric space and flavour factors but an antisymmetric colour factor. The Pauli exclusion principle therefore requires a symmetric spin factor: the pair has .
The angular momentum identitygivesNext couple to , where . For total ,For the spin- Xi baryon, this is . By symmetry the two pair correlations are each . Inserting the pair correlations into the baryon hyperfine mass formula givesFor the spin- state, the same coupling gives . Each pair correlation is therefore , as expected for a fully symmetric spin state. HenceThe predicted splitting is a useful independent check:
Use GeV consistently with the supplied :The spin-independent sum is . The spin-spin interaction corrections areThusThe displayed decimal places document the calculation, rather than asserting that this simple constituent-quark model has sub-MeV predictive precision.
The predicted-minus-measured differences areRelative to the measured masses, these are and . The predicted spin-spin interaction splitting is , compared with the measured , a discrepancy of about in the splitting.
This is an effective constituent-quark model, with a common spatial contact factor and a nonrelativistic spin-dependent interaction applied to light quarks. Relativistic motion, different spatial wavefunctions, and omitted strong-interaction corrections prevent an expectation of accuracy at the experimental -- scale. Agreement at the level of several percent in absolute baryon masses would already be useful for such a simple formula; the sub-percent absolute-mass agreement here is better than that rough expectation.
No theoretical uncertainty or fitting prescription is supplied, so there is no unique numerical “expected error” or justified statistical significance to attach to the deviations. Small relative errors in the large spin-independent mass sum also need not imply equally small relative errors in the much smaller spin-spin interaction splitting.
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