Past exam of the physics A course of the University of Cambridge / 2015 / Paper 2 / Section C / C11 / Solution

Write the real displacement as $U_n(t)=\mathrm{Re}[u{e}^{i\omega t-iqna}]$, choosing real positive peak amplitude $u$. Nearest-neighbour harmonic springs store energy in their extension $U_n-U_{n+1}$, each spring counted once. Therefore the instantaneous physical energy isThe printed complex displacement is a calculation device: squaring the complex phasor itself would not produce physical energy. The chain sketch in the accompanying figure shows masses at equilibrium spacing $a$, with longitudinal displacements along the chain.

The two spring forces on site $n$ giveSubstituting the normal-mode phasor and cancelling its nonzero amplitude givesThe long-wavelength limit is acoustic, $\omega \simeq a\sqrt{\alpha /M}|q|$, and the first Brillouin zone ends at $|q|=\pi /a$. The maximum angular frequency is ${\omega }_m=2\sqrt{\alpha /M}$.

Time averaging uses $⟨[\mathrm{Re}(z{e}^{i\omega t}){]}^2⟩=|z{|}^2/2$. ConsequentlyThe dispersion relation makes these two contributions equal, givingThis is equality of time-averaged kinetic and potential energies in a harmonic normal mode; the instantaneous energy partition need not be equal.

Use periodic boundary conditions on length $L=Na$ to count modes: $q_j=2\pi j/L$. The density on the signed $q$ axis is $L/(2\pi )$. Using folded wave-number counting for a monatomic chain combines $q$ and $-q$ at positive magnitude and counts both directions, so the convention used by the requested expression isThis is a large-$N$ continuum density, not a second independent branch. It gives $N$ modes after integrating over that half-zone; endpoint counting changes only finite-size corrections.

For positive $q$, $\omega ={\omega }_m\sin (qa/2)$ andThe density of states of a monatomic harmonic chain vanishes outside the band, is constant to leading order near zero, and has an integrable Van Hove singularity at the upper band edge where group velocity vanishes. Normalization checks the directional counting: