Equation and boundary conditions. The delta potential has strength with units of energy times length, because the Dirac delta function has units of inverse length. The Time-independent Schrödinger equation isThe wavefunction is continuous at the origin. A finite jump in would produce a derivative of a Dirac delta function in , with no corresponding term in this potential. A jump in does produce a delta contribution and is allowed. Integrate through a symmetric interval:For continuous finite , the right-hand side vanishes as . ConsequentlyThis derivative jump is the boundary condition associated with the attractive delta potential.
Unique bound state. For , write . Away from the origin, . Normalizability excludes exponentials growing at either infinity, leavingContinuity gives . The derivative jump then becomes . For a nonzero state,There is exactly one positive value of , so exactly one negative-energy bound state. An odd solution would have ; the allowed decaying exponentials would then both vanish identically. Normalize the even solution usingChoosing the overall phase real and positive gives the bound state in a delta potential:It peaks at the origin, has a downward cusp there, and decays exponentially on both sides. Its value, but not its slope, is continuous.
Scattering amplitudes and fluxes. For , put and retain as a strength parameter. A unit-amplitude wave incident from the left hasContinuity gives . The jump condition givesSolving,The probability current of a plane wave of amplitude is in its propagation direction. Since the asymptotic wavenumber is the same on both sides, reflection probability and transmission probability are just and :They satisfy , expressing conserved probability current in this real potential.
The normalized delta-well bound state and reflection/transmission probabilities as attraction increases
. Details. The right-hand plot uses , proportional to at fixed incident energy. Then rises monotonically from zero to one, while falls from one to zero; they are equal at . Despite the absence of a classical forbidden barrier, an abrupt attractive interaction reflects a quantum wave. Increasing attraction strengthens the derivative mismatch and can approach complete reflection at fixed positive energy. At fixed , increasing incident energy instead makes the well increasingly transparent. The negative-energy bound state and the positive-energy scattering states are different stationary solutions, not an absorptive loss channel.
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