The occupation probability of an individual one-electron state is the Fermi-Dirac distribution,
At , it is a step: one below and zero above it. Heating rounds the step over an energy range of order a few , creating empty states below and occupied states above the chemical potential. At every positive temperature, .
For fixed in the three-dimensional free electron model, the chemical potential is determined by ; it is not exactly constant. In the degenerate regime , the Sommerfeld expansion gives
It is therefore reasonable in a simple low-temperature sketch to set , provided this approximation is stated. The figure includes the leading small shift. At much higher temperature the fixed- approximation fails and the distribution approaches the classical dilute limit. The plotted occupation is , rather than the energy distribution .
Figure 1.
Thermal rounding of Fermi-Dirac occupations at fixed particle number, with the leading chemical-potential shift
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