The internal energy is the canonical mean of the energy:Holding the external mechanical parameters fixed, so that the spectrum and degeneracies do not change when differentiating with respect to , givesComparison yieldsAn explicitly temperature-dependent effective Hamiltonian would require care: differentiating its partition sum would also differentiate the assigned energy levels. The stated result uses the fixed physical spectrum of the canonical system.
Articles by others on the same topic
There are currently no matching articles.