Fixed endpoints require , with . Writing ,For equal amplitudes , the two requested profiles areThe first is asymmetric, with an interior zero at ; the second has its interior node at . For two-mode string recurrence, orthogonality means the whole initial profile recurs only when both cosine coefficients equal one. Since ,
Two-mode string profiles and the small change produced by weak positive dispersion at the original quarter-period
. Details. The weak-stiffness string frequency shift follows by expanding the supplied dispersion relation:Higher normal modes acquire larger fractional frequency shifts. Let and retain for the original ideal frequency. At the originally defined time ,Thus the sketch is unchanged, whereas the original quarter-period sketch gains a small negative fundamental component. If is redefined using the new fundamental frequency, its fundamental component is exactly zero and the second-mode change there is only second order. Both conventions agree that generic later shapes change because of relative phase drift.
The new frequency ratio isAn exact recurrence now requires and for integers . If in lowest terms, the first recurrence is ; for irrational there is no exact finite recurrence. Near-recurrences remain possible. Positive stiffness alone does not prove that the ratio is irrational.
Here is potential energy, is the stationary-state total energy eigenvalue, and is its spatial wavefunction. Wavefunction normalization gives , and is the probability of finding the particle in .
A bound state requires . Inside the well the equation is , whereas outside it is , withThe ground state is even and has no node, selecting inside. Normalizability selects decaying, not growing, exterior exponentials. Continuity of and givesThe first excited state, if present, is odd: a sine inside and opposite-sign decaying tails outside. Matching gives . On its first odd branch, , hence . Since , existence requiresThis is the first odd bound-state threshold of a square well. There is no excited bound state below that threshold; equality gives a non-normalizable zero-energy limiting state, not an extra bound state.
Original finite-well wavefunctions: an even nodeless ground state and an odd excited state in a deeper illustrative well
. Details. For the numerical well,The exterior probability of a symmetric finite-well state includes both tails:The threshold is , exceeding the well depth, so there is no excited bound state. The rounded supplied coefficients integrate to rather than exactly one; this rounding does not change the quoted probability precision materially.
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